Two new complexes,C9H7NO3)Zn(C3H4N2)2(1) and(C9H7NO3)Ni(C3H4N2)2(C4H5N2O)·CH3OH·0.5H2O(2),with salicylideneglycinyl as the ligands,were synthesized successfully at room temperature in methanol solution,and characterized via elemental analyses,IR spectra,UV-Vis and fluorescence spectra,and X-ray diffraction and thermogravimetric analyses were also carried out.
A mixing solution of the prepared acetylferrocene and S-benzyl-N-Dithiocarbazate in ethanol with 1∶1 mole ratio is kept on reflux in water bath.Then the goal compound S-benzyl-N,N’-(ferrocenyl-1-methyl-metylidene)-Dithiocarbazate(HLSB)is obtained.The structure of title amplex is characterized by IR spectra,UV spectra.A Schiff base compound with phenyl-and ester alkyl is synthesized.The compound consist of one-dimensional chain that is linked together by a kind of weak H-bonding(N1-H1B——S1A(-x+1,y+1/2,-z+1/2)).
