A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecane and decatungstate polyanions.HR-TEM image ahowded that the decatungstate polyanions"packed"around the l,10-diaminodecane moledules.XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown).Atdlplate mechanosm was pro-posed to explain its formation prodess.It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework.the cationic diaminodecane molecules "bond"decatungstate polyanions on esch end via supermolecular interation and thus form bolarform struc-ture units.These units pack together and ahexagonal phasa is constructed.
Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers.TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism,a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.
