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李英芝

作品数:2 被引量:8H指数:1
供职机构:天津大学化工学院天津化学化工协同创新中心更多>>
发文基金:国家自然科学基金更多>>
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Plasma methods for preparing green catalysts: Current status and perspective被引量:8
2016年
Most current catalyst preparation methods cause pollution to air, water and land with the use of hazardous chemicals, lengthy operation time, high energy input and excessive water usage. The development of green catalyst preparation is necessary to prevent and eliminate waste from each step of the catalyst preparation. We summarize recent progress in the application of cold plasmas for green catalyst preparation. Cold plasma preparation can reduce the catalyst size, improve the dispersion and enhance catalyst-support interaction with the use of less or no hazardous chemicals. These improvements also lead to the enhancement of catalyst activity and stability. An alternative room temperature electron reduction with a non-hydrogen plasma as an electron source was developed for the reduction of noble metal ions in which no hazardous chemical reducing agent or hydrogen was needed. This creates many opportunities for the development of supported catalysts with heat sensitive substrates, including metal organic frameworks (MOFs), covalent organic framework(COFs), high surface area carbon, peptide, DNA, proteins and others. A novel floating metal catalyst on a water(or solution) surface has been established. Template removal using low temperature cold plasmas also leads to the formation of high surface area porous materials with characteristics that are normally only obtainable with high temperature calcination, but sintering can be avoided. Micro combustion has been developed for the removal of carbon template using cold plasma. This is promising for preparing many structured oxides in a simple way with no use of auxiliary chemicals. Many opportunities exist for the use of cold plasmas to make multi-metallic oxides. Some future development ideas are addressed.
刘昌俊李敏悦王嘉琪周昕瞳郭秋婷严金茂李英芝
关键词:PLASMA
等离子体影响下纳米银颗粒的制备与表征
<正>纳米材料由于其粒子的尺寸进入到纳米量级,使其具有不同于传统固体材料的特殊性质。以金、银、铂、钯为代表的贵金属纳米颗粒的制备是纳米材料研究的一个重要分支。纳米银颗粒,由于具有很高的表面活性、表面能和催化性能,可应用于...
李英芝叶静云刘昌俊
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