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陈文韬

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供职机构:中国科学技术大学化学与材料科学学院化学物理系更多>>
发文基金:中国博士后科学基金更多>>
相关领域:理学更多>>

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High-Resolution Experimental Study on Photodissocaition of N2O
2016年
We study the photodissociation dynamics of nitrous oxide using the time-sliced ion veloc- ity imaging technique at three photolysis wavelengths of 134.20, 135.30, and 136.43 nm. The O(^1Sj=0)+N2(XI∑g+) product channels were investigated by measuring images of the O(iSj=0) products. Vibrational states of N2(XI∑g+) products were fully resolved in the images. Product total kinetic energy releases (TKER) and the branching ratios of vibrational states of N2 products were determined. It is found that the most populated vibrational states of N2 products are v--2 and v--3. The angular anisotropy parameters (8 values) were also derived. The β values are very close to 2 at low vibrational states of the correlated N2 (X1 ∑g+) products at all three photolysis wavelengths, and gradually decrease to about 1.4 at v--7. This indicates the dissociation is mainly through a parallel transition state to form products at lower vibrational states, and the highly vibrational exited products are from a more bent configuration. This is consistent with the observed shift of the most intense rotational structure in the TKER as the vibrational quantum number increases.
俞盛锐袁道福陈文韬谢婷王思雯杨学明王兴安
关键词:N2OPHOTODISSOCIATION
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