您的位置: 专家智库 > >

文献类型

  • 1篇中文期刊文章

领域

  • 1篇理学

主题

  • 1篇N2O
  • 1篇EXPERI...
  • 1篇PHOTOD...
  • 1篇HIGH-R...

机构

  • 1篇中国科学院
  • 1篇中国科学技术...

作者

  • 1篇杨学明
  • 1篇袁道福
  • 1篇王思雯
  • 1篇谢婷
  • 1篇王兴安
  • 1篇陈文韬

传媒

  • 1篇Chines...

年份

  • 1篇2016
1 条 记 录,以下是 1-1
排序方式:
High-Resolution Experimental Study on Photodissocaition of N2O
2016年
We study the photodissociation dynamics of nitrous oxide using the time-sliced ion veloc- ity imaging technique at three photolysis wavelengths of 134.20, 135.30, and 136.43 nm. The O(^1Sj=0)+N2(XI∑g+) product channels were investigated by measuring images of the O(iSj=0) products. Vibrational states of N2(XI∑g+) products were fully resolved in the images. Product total kinetic energy releases (TKER) and the branching ratios of vibrational states of N2 products were determined. It is found that the most populated vibrational states of N2 products are v--2 and v--3. The angular anisotropy parameters (8 values) were also derived. The β values are very close to 2 at low vibrational states of the correlated N2 (X1 ∑g+) products at all three photolysis wavelengths, and gradually decrease to about 1.4 at v--7. This indicates the dissociation is mainly through a parallel transition state to form products at lower vibrational states, and the highly vibrational exited products are from a more bent configuration. This is consistent with the observed shift of the most intense rotational structure in the TKER as the vibrational quantum number increases.
俞盛锐袁道福陈文韬谢婷王思雯杨学明王兴安
关键词:N2OPHOTODISSOCIATION
共1页<1>
聚类工具0