Ecological reactive powder concrete (ECO-RPC) with small sized and differentvolume fraction steel fibers was prepared by substitution of ultra-fine industrial waste powder for50% to 60% cement by weight and replacement of ground fine quartz sand with natural fine aggregate.The effect of steel fiber volume fraction and curing ages on the static mechanical behaviour ofECO-RPC was studied. Using the split Hopkinson pressure bar technique, the dynamic mechanicalbehaviour of ECO-RPC was investigated under different strain rates. The results show that the staticmechanical behaviour of ECO-RPC increases with the increase of steel fiber volume fraction andcuring ages. The type of ECO-RPC with the substitution of 25% ultra-fine slag, 25% ultra-fine flyash and 10% silica fume is better than the others with compressive strength, flexural strength, andfracture energy more than 200 MPa, 60 MPa and 30 kJ/m^2, respectively. ECO-RPC has excellent strainrate stiffening effects under dynamic load. Its peak stress, peak strain and the area understrain-stress curve increase with the increase of strain rate. Its fracture pattern changes frombrittleness to toughness under high strain rates.