Tetra(4-diazoniumbenzene)porphyrin(TDBP) was synthesized via diazo-reaction of tetra-(4-aminobenzene)porphyrin(TABP). From the analysis results of MALDI-TOF mass spectroscopy and FTIR,it was confirmed that the synthesized porphyrin derivative mainly consists of tetra(4-diazoniumbenzene) porphyrin with trace tri- and di-substituted compounds. The self-assembly of TDBP with poly(styrene sulfonate)(PSS) was carried out and a novel TDBP/PSS multilayer ultrathin film on silicon substrate was obtained. The self-assembled film is very sensitive to heat and light,after heating or irradiation of UV light,the thin film becomes very stable towards polar solvents such as DMF. The coupling reaction of TDBP with phenol and the thermal stability of TDBP were also investigated preliminary. [WT5HZ]
The self-assembly between poly(4-diazonium styrene) (PDS) and poly(sodiumsulfonate styrene)(PSS) was investigated.The mutilayer ult ra thin films were fabricated layer-by-layer successfully from PDS and PSS.Af ter heating for 10 min at 70℃ the multilayer film became very stable towards po lar solvents.No considerable changes were observed for the heated film soaked i n DMF (20℃) for 48 h,while the unheated film almost destroyed at same conditio n.The dramatic improvement in stability of the film towards polar solvents shou ld be attributed to the conversion of bonds between the layers of the film from ionic bond to covalent bond under heating.Y(4 DIAZONIUMSTYRENE)ANDPOLY(SODIUMSULFONATESTYRENE)YANGZhaohui,JIANGWei,CAOWeixiao(CollegeofChemistryandMolecularEngineering ,PekingUniversity ,Beijing 10 0 871)Abstract Theself assemblybetweenpoly( 4 diazoniumstyrene) (PDS)andpoly(sodiumsulfonatestyrene) (PSS)wasinvestigated .Themutilayerultrathinfilmswerefabricatedlayer by layersuccessfullyfromPDSandPSS .Afterheatingfor 1 0minat 70℃themultilayerfilmbecameverystabletowardspolarsolvents.NoconsiderablechangeswereobservedfortheheatedfilmsoakedinDMF ( 2 0℃ )for48h ,whiletheunheatedfilmalmostdestroyedatsamecondition.Thedramaticimprovementinstabilityofthefilmtowardspolarsolventsshouldbeattributedtotheconversionofbondsbetweenthelayersofthefilmfromionicbondtocovalentbondunderheating .Keywords Poly( 4 diazoniumstyrene) 。
