A storage and emission functional material of [Ca24Al28O64]^4＋·（Cl^-）3.80（O^2-）0.10 （C12A7-Cl^-）, was prepared by the solid-state reactions of CaCO3, γ-Al2O3, and CaCl2 in Cl2/Ar mixture atmosphere. The anionic species stored in the C12A7-Cl^- material were dominated by Cl^-, about （2.21±0.24） × 10^21 cm^-3, accompanied by a small amount of O^2-, O^-, and O2^-, measured via ion chromatography, electron paramagnetic resonance, and raman spectra measurements. These results also corroborate identification of time-of-flight mass spectroscopy--the anionic species emitted from the C12A7-Cl^- surface were dominated by the Cl^- （about 90%） together with a small amount of O^- and electrons. The structure and morphological alterations of the material were investigated via X-ray diffraction and field emission scanning electron microscope, respectively.
High-efficient production of hydrogen from bio-oil was performed by electrochemical catalytic reforming method over the CoZnAl catalyst. The influence of current on the hydrogen yield, carbon conversion, and products distribution were investigated. Both the hydrogen yield and carbon conversion were remarkably enhanced by the current through the catalyst, reaching hydrogen yield of 70% and carbon conversion of 85% at a lower reforming temperature of 500 ℃. The influence of current on the properties of the CoZnAl catalyst was also characterized by X-ray diffraction, X-ray photoelectron spectroscopy, thermal gravimetric analysis, and Brunauer-Emmett-Teller measurements. The thermal electrons would play an important role in promoting the reforming reactions of the oxygenated-organic compounds in the bio-oil.
