利用碳原子线(CAWs)上的羧基与2-巯基乙胺的氨基发生选择性缩合反应生成巯基化碳原子线,并用红外光谱对反应进程及一些反应条件的影响进行表征.实验结果表明:10 mg经浓硝酸氧化处理过的碳原子线在含有20 mg巯基乙胺、10 mL CH2Cl2、1 mL N(Et)3(三乙胺)、0.2 g DCC(二环己基碳化二亚胺)的液相反应体系中,60℃温度下作用24 h可完成缩合反应,生成巯基化碳原子线.在该巯基化过程中,CAWs的特征碳链结构并未发生可觉察的变化.
Gd2O3∶Tb3+ luminescent nanoparticles were prepared by the thermal decomposition of the nanosized oxlate prepared in the reverse microemulsions based on triton X-100/n-hexyl alcohol, n-octane, and water. From TG-DTA, XRD and FTIR analyses, the mechanism of thermal decomposition of the nanosized oxalate precursor is suggested as follows: Gd2(C2O4)3·10H2O → Gd2(C2O4)3 + 10H2O, Gd2(C2O4)3 → Gd2O2(CO3) + 3CO +2CO2, Gd2O2(CO3) → Gd2O3 + CO2. The kinetic parameters of thermal decomposition reaction-activation energy E of stage 2 and 3 are 194.6 kJ·mol-1, 110.9 kJ·mol-1, respectively, using Ozawa method. And the reaction order n is 2.9 and 0.43, respectively, according to the TG curves.
