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广东省自然科学基金(06105562)

作品数:3 被引量:16H指数:2
相关作者:陈鸣才祝纶宇王洪更多>>
相关机构:绵阳师范学院更多>>
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锂离子电池正极材料LiCoO_2的包覆改性被引量:12
2007年
以Mg-PAA为原料,采用溶液法在LiCoO2表面包覆一层均匀稳定的MgO层。用X射线衍射、扫描电子显微镜和俄歇能谱等测试技术对包覆前后的LiCoO2的结构和性能进行了表征。结果表明,处理后在LiCoO2的表面形成了LiCo1-xMgxO2固溶液,此固溶液保护层减少了LiCoO2和电解液直接接触,有效地抑制了LiCoO2与电解液的相互作用。经表面修饰处理后,LiCoO2正极材料的结构有序度、稳定性及材料的电化学性能均得到明显提高。处理LiCoO2所制电池在1C电流、4.3和4.4 V经100次循环,容量衰减只有5%和6.5%。
王洪祝纶宇陈鸣才
关键词:LICOO2锂离子电池正极材料
Effects of SrO/Li_2O/La_2O_3/Ta_2O_5/TiO_2-coating on electrochemical performance of LiCoO_2
2009年
Commercial cathode material (LiCoO2) was modified by coating with a thin layer of SrO/Li2O/La2O3/Ta2O5/TiO2 for improving its performance in lithium ion battery. The morphology and structure of the modified cathode material were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The performance including cycling stability, diffusion coefficient under different voltage, C-rate discharge of the batteries with this modified cathode material was examined. The results showed that the battery with the coated cathode material could discharge at a large current density, and it possessed a stable cycle performance in the range from 3.0 V to 4.2 V. It was explained that the rate of Li ion diffusion increased in the batteries using SrO/Li2O/La2O3/Ta2O5/TiO2-coated LiCoO2 as the cathode and the coated layer could act as a fast ion conductor (SrO/Li2O/La2O3/Ta2O5/TiO2) and as a protecting shell to prevent LiCoO2particles from being attacked by the acidic electrolyte.
王洪邓璋琼陈鸣才
Effects of La_2O_3/Li_2O/TiO_2-Coating on Electrochemical Performance of LiCoO_2 Cathode被引量:4
2007年
Conventional cathode material (LiCoO2) was modified by coating with a thin layer of La2O3/Li2O/TiO2 for improving its performance for lithium ion battery. The morphology and structure of the modified cathode material was characterized by SEM, XRD, and Auger electron spectroscopy. The performance of the cells with the modified cathode material was examined, including the cycling stability, the diffusion coefficient under different voltages, and the C-rate discharge. The results showed that the cell composed of the coated cathode material discharged at a large current density, and possesses a stable cycle performance in the range from 3.0 to 4.4 V. It was explained that the rate of Li ion diffusion increased in the cell while using La2O3/Li2O/TiO2-coated LiCoO2 as the cathode and the coating layer may act as a faster ion conductor (La2O3/Li2O/TiO2).
王洪祝纶宇陈鸣才
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