77 K nitrogen adsorption was the most widely used technique for determining surface area and pore size distribution of coal. Brunauer–Emmett–Teller(BET) and Barrett–Joyner–Halenda(BJH) model are commonly used analytic methods for adsorption/desorption isotherm. A Chinese anthracite coal is tested in this study using an improved experimental method and adsorption isotherm analyzed by three adsorption mechanisms at different relative pressure stages. The result shows that the micropore filling adsorption predominates at the relative pressure stage from 6.8E 7 to 9E 3. Theoretically, BET and BJH model are not appropriate for analyzing coal samples which contain micropores. Two new analytic procedures for coal surface area and pore size distribution calculation are developed in this work. The results show that BET model underestimates surface area, and micropores smaller than 1.751 nm account for 35.5% of the total pore volume and 74.2% of the total surface area. The investigation of surface area and pore size distribution by incorporating the influence of micropore is significant for understanding adsorption mechanism of methane and carbon dioxide in coal.
Based on the basic theory of gas seepage and coal seam deformation, using the numerical simulation method, this paper established the gas-solid coupling model of gas drainage from borehole. Using multi-physical coupling analysis software, the authors studied the stress change conditions around the drainage borehole, the influence of the gas drainage effect caused by the drilling gap, and the gas drainage effect under the conditions of different borehole radius and different permeabilities. The results show that the effective drainage radius is 1.03 m during 30 days of drainage. The effect of the diameter change of the drainage borehole is limited, but the influence of coal seam permeability is much bigger. After the same drainage period, the greater the permeability of coal seam is, the bigger the drainage radius is. For a low permeability coal seam, coal miners should take pressure-relief measures and increase the permeability to improve the drainage effects before draining gas through drilling.
