The influence of nano-A!2O3 additive on the adhesion between epoxy resin and steel substrate has been investigated. The results of tensile testing indicated that the adhesion strength was increased dramatically by addition of Al2Os nanoparticles in epoxy resin compared with that of the unmodified resin. The highest adhesion strength was obtained with 1 wt% nano-A!2O3 added in epoxy adhesive, more than two times higher than that of the unmodified. Scanning electronic microscope (SEM) revealed that a boundary layer exists between epoxy and steel substrate, energy spectrum analysis indicates there is enrichment of the nano-A!2O3 particle. Those results confirmed that the nano-A12O3 additive was closely related to the change of interface morphology and the improvement of adhesion strength. The reason for adhesion improvement was also be discussed.