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国家自然科学基金(10275048)

作品数:4 被引量:3H指数:1
相关作者:张端明郑克玉杨凤霞徐洁李丽娟更多>>
相关机构:华中科技大学湖北大学襄樊学院更多>>
发文基金:国家自然科学基金更多>>
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Competition between aggregation and migration processes of a multi-species system
2005年
We propose a solvable multi-species aggregation-migration model, in which irreversible aggregations occur between any two aggregates of the same species and reversible migrations occur between any two different species. The kinetic behaviour of an aggregation-migration system is then studied by means of the mean-field rate equation. The results show that the kinetics of the system depends crucially on the details of reaction events such as initial concentration distributions and ratios of aggregation rates to migration rate. In general, the aggregate mass distribution of each species always obeys a conventional or a generalized scaling law, and for most cases at least one species is scaled according to a conventional form with universal constants. Moreover, there is at least one species that can survive finally.
柯见洪庄友谊林振权叶鹏
关键词:AGGREGATIONMIGRATION
0-3型(PZT,KTN)/P(VDF-TrFE)三相铁电复合材料的电学性能
2008年
以偏氟乙烯-三氟乙烯(P(VDF-TrFE))共聚物为基体,锆钛酸铅(PZT)铁电颗粒为功能相,钽铌酸钾(KTN)颗粒为增强相,制备了0-3型(PZT,KTN)/P(VDF-TrFE)三相铁电复合材料。利用SEM及EDAX技术,分析了复合材料的显微结构及PZT和KTN相的分布。测试了具有不同KTN体积分数的复合材料的电性能。实验结果表明:PZT和KTN相的颗粒分布均匀,存在少量的团聚体;随KTN体积分数的增加,三相复合材料的极化漏电流I、介电常数rε和介电损耗tanδ增加,压电系数d33降低,而热释电系数p3先增加后降低,但其d33和p3均高于具有相同PZT体积分数的PZT/P(VDF-TrFE)两相复合材料。
杨凤霞张端明韩祥云姜胜林钟志诚郑克玉
关键词:聚合物复合材料压电性热释电性介电性
硒化银纳米颗粒和晶体的制备及其表征被引量:3
2008年
以氯化纳和硒粉为原料,乙二胺为反应溶剂,通过室温合成法制备了硒化银(Ag2Se)纳米颗粒,并首次利用固相反应法,在300℃~600℃烧结范围合成了晶体。结合X射线粉末衍射(XRD)、扫描电镜SEM及透射电镜(TEM)分别对反应产物的相结构和形貌进行了表征。结果表明,室温合成法所得产物为高纯度的正交仪相Ag2Se纳米颗粒,其表面光滑,呈球形;固相反应法合成的样品保持了正交相结构,且Ag与Se的化学计量比基本满足2:1。
杨凤霞邓宗伟张端明郑克玉李丽娟徐洁
关键词:固相反应法
Aggregation processes with catalysis-driven monomer birth/death
2006年
We propose two solvable cluster growth models, in which an irreversible aggregation spontaneously occurs between any two clusters of the same species; meanwhile, monomer birth or death of species A occurs with the help of species B. The system with the size-dependent monomer birth/death rate kernel K(i, j) = Jijv is then investigated by means of the mean-field rate equation. The results show that the kinetic scaling behaviour of species A depends crucially on the value of the index v. For the model with catalysis-driven monomer birth, the cluster-mass distribution of species A obeys the conventional scaling law in the v ≤ 0 case, while it satisfies a generalized scaling form in the v ≥ 0 case; moreover, the total mass of species A is a nonzero value in the v 〈 0 case while it grows continuously with time in the v ≥ 0 case. For the model with catalysis-driven monomer death, the cluster-mass distribution also approaches the conventional scaling form in the v 〈 0 case, while the conventional scaling description of the system breaks down in the v ≥ 0 case. Additionally, the total mass of species A retains a nonzero quantity in the v 〈 0 case, but it decreases to zero with time in the v ≥ 0 case.
陈玉韩安家柯见洪林振权
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