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国家自然科学基金(50971120)

作品数:3 被引量:19H指数:3
相关作者:王雷董俊华柯伟更多>>
相关机构:中国科学院金属研究所更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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Mn-Cu-P耐候钢锈蚀规律及其锈层结构与性质关系的研究
利用干湿循环加速腐蚀实验方法研究了Mn-Cu低合金钢在模拟海岸大气条件下的锈蚀演化规律。结果表明,在初期锈蚀速度随干湿循环次数的增加而增大,随后转为随干湿循环次数的增加而降低。带锈Mn-Cu低合金钢的电化学极化行为表明,...
董俊华柯伟
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In Situ Corrosion Monitoring of Mild Steel in a Simulated Tidal Zone without Marine Fouling Attachment by Electrochemical Impedance Spectroscopy被引量:11
2014年
The corrosion behaviors of the isolated short and vertical long scale Q235B steel in a simulated tidal zone were studied by electrochemical impedance spectroscopy (EIS) monitoring and corrosion weight loss calculation in an experimental indoor simulating trough. The results show that the corrosion rate of the isolated short scale Q235B steel in the tidal zone acquired by the EIS agrees with the corrosion weight loss result. The corrosion rates of the short scale steel are in the order of middle tidal zone 〉 the central zone between the middle tidal zone and low tidal zone 〉 high tidal zone 〉 low tidal zone. The fastest corrosion rate in the middle tidal zone is attributed to the longest wet time in a tidal cycle. According to the comparison of corrosion weight loss between the vertical long scale and isolated short scale specimens, the corrosion rate of vertical long scale specimens of Q235B steel is lower than that of the isolated short scale specimens in the tidal zone, but the result is contrary in the immersion zone.
Xin MuJie WeiJunhua DongWei Ke
Numerical Approach for Atmospheric Corrosion Monitoring Based on EIS of a Weathering Steel被引量:4
2015年
Electrochemical impedance spectroscopy (EIS) and film thickness measurement have been employed to study the atmospheric corrosion of a weathering steel covered with a thin electrolyte layer in a simulated coastal-industrial atmosphere. The results indicate that the corrosion rate is a function of the covered electrolyte thickness and the wet/dry cycle. Within each wet/dry cycle, the increased corrosion rate is related to the increased Cl^- and SO4^2- concentration and an enhancement of oxygen diffusion rate with the evaporation of the electrolyte. In addition, the corrosion rate increases during the initial corrosion stage and then decreases as the wet/dry cycle proceeds. Moreover, one mathematical approach based on the numerical integration method to obtain corrosion mass loss of steel from the measurements of EIS has been developed, and this would be useful for the development of indoor simulated atmospheric corrosion tests.
Ch.TheeLong HaoJun-Hua DongXin MuWei Ke
加载与循环干湿条件下MnCu耐候钢的腐蚀行为被引量:4
2010年
同时采用循环加载及模拟加速腐蚀的方法,研究循环载荷对耐候钢在含氯离子气氛中腐蚀行为的影响。锈层截面形貌以及带锈电极的电化学极化行为和阻抗谱表明,在相同的拉伸时间内,腐蚀周次较低时,耐候钢能较快获得稳定的锈层;腐蚀周次较高时,在长时间的循环载荷影响下,MnCu耐候钢的外锈层会更易产生裂纹甚至脱落,但内锈层结构相对稳定而基本不受一般载荷的影响,因此MnCu耐候钢依然具有良好的耐候性。
王雷董俊华柯伟
关键词:循环加载电化学测量锈层
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