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国家自然科学基金(21073187)

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相关作者:陈旸张群张志国黄存顺张翠梅更多>>
相关机构:中国科学技术大学中国科学院更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
相关领域:理学更多>>

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Helium Droplets: An Apparatus to Study Ultra Cold Chemistry
2013年
A new pulsed helium nano droplets machine has been constructed. The droplets were gener- ated by expansion of the pure helium through the cryogenic valve attached to a closed-cycle cryostat. The mean size of helium droplets can be controlled between 103 and 105 helium atoms by tuning the backing pressure (10-40 bar) and temperature (10-30 K). Compared with the continuous-flow beam source, the density of droplet is at least one order of magni- tude higher, which offers the opportunity to combine the system with the commercial pulsed laser to study chemical reactions inside of the superfluid helium at ultra-low temperature. The performance for the system has been checked by studying the photodissociation of CH3I doped droplets at 252 nm with the velocity map imaging technique. The photofragments, CH3, were detected by (2+1) resonance enhanced multiphoton ionization. The speed and angular distributions derived from resulting images show clear evidence of the relaxation effect by the surrounding helium atoms. The pulsed helium droplets depletion spectroscopy was also demonstrated. The depletion spectrum of benzene doped helium droplets indicates that less than 3% depletion can be observed with the newly constructed apparatus.
张翠梅张志国黄存顺张群陈旸
氦液滴中羰基硫分子的光解动力学(英文)
2013年
用时间切片速度成像方法研究了氦液滴中羰基硫(COS)分子的光解动力学.从共振增强(2+1)电离的CO光谱中发现在氦液滴环境中解离产物CO的转动冷却比振动冷却更有效.利用速度成像采集到的CO(ν=0)和CO(ν=1)的影像在角分布上都呈现出各向同性的特点.产物平动能分布的结果表明尽管大部分的平动能都被超流体环境所弛豫,但振动激发态产物CO(ν=1)的平均平动能比振动基态产物CO(ν=0)的平均平动能高.对羰基硫分子在氦液滴中的光解动力学机理进行了讨论.
张翠梅张志国黄存顺张群陈旸
关键词:羰基硫
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