Some metamorphic relations (MR) are not good at detecting faults in metamorphic testing. In this paper, the method of making compositional MR (CMR) based on the speculative law of proposition logic is presented. This method constructs new MRs by composing existing MRs in a pairwise way. Because CMR contains all the advantages of the MRs that form it, its fault detection performance is wonderful. On the other hand, the number of relations will decrease greatly after composing, so a program can be tested with much fewer test cases when CMRs are used. In order to research the characteristics of a CMR, two case studies are analyzed. The experimental results show that the CMR's performance is mostly determined by the central MRs forming it and the sequence of composition. Testing efficiency is improved greatly when CMRs are used.