A one-time programmable metal-molecule-metal device, with a modified Rotaxane LB film as the functional layer, is proposed for potential use in organic programmable and fault tolerant circuits like inorganic anti-fuse devices used in field programmable gate arrays. All fabrication methods involved are low temperature processes, ensuring that this device can be integrated with other organic devices. Electrical measurements show that this device has a good one-time programming capability. Its break down voltage is 2.2V, off-state resistance is 15kΩ, and on-state resistance is 54Ω These characteristics come from the penetration of metal atoms into molecular film under high electronic field.
The AgTCNQ thin-film was prepared by vacuum vapor co-deposition and characterized by infrared spectral analysis,and then a uniform AgTCNQ （TCNQ-- 7,7,8,8-tetracyanoquinodimethane） thin-film layer was sandwiched in a Ti/AgTCNQ/Ati crossbar structure array as organic bistable devices （OBD）.A reversible and reproducible memory switching property,caused by intermolecular charge transfer （CT） in the AgTCNQ thin-film, was observed in the organic bista- ble devices. The positive threshold voltage from the high impedance state to the low impedance was about 3.8-5V, with the reverse phenomenon occurring at a negative voltage of - 3.5- - 4. 4V,lower than that with a CuTCNQ active layer. The crossbar array of OBDs with AgTCNQ is promising for nonvolatile organic memory applications.
Based on the orthodox theory,a model of a single electron transistor （SET） of metallic tunneling junctions is built using the master equation method. Several parameters of the device, such as capacitance, resistance and temperature,are input into the model and thus the I-V curves are attained. These curves are consistent with those from other experiments; therefore, the model is verified. However, there still exists a difference between simulated results and experimental results,mainly comes from the stationary case of the master equation. In other words, precision of simulated results would be increased if the transient case of the master equation is considered. Moreover, the current increases exponentially at higher drain voltages, which is due to the fact that the barrier suppression is caused by the image charge potential.
