The calcined magnesite was utilized as a kind of MgO bearing additive to produce MgO bearing pellets. The effects of MgO on densification and consolidation of pellets were investigated. The experimental results show that, at the same process parameters, the porosity and pore size distribution of green pellets have no evident relation with the MgO bearing additive, pore size of green pellets is between 15 μm and 35 μm and the porosity of green pellets is about 34%. There is a densification and consolidation phenomenon during the induration process; the pore size and porosity of product pellets decrease gradually; and the structure of product pellets becomes dense. MgO makes a negative effect on the densification and consolidation of product pellets, the densification ratio of pellets decreases from 46.3% to 28.6% with the addition of MgO bearing additive from 0 to 2.0 %. The porosity and the pore size of product pellets increase gradually with the increase of MgO content; When the mass fraction of MgO bearing additive increases from 0 to 2.0%, the pore size of product pellet increases and the pore size distributes in a large range. Also, the porosity increases from 18.61% to 24.06%.
The reduction process of MgO-fluxed pellets was investigated and compared with traditional acidic pellets in this paper.Based on the piston flow concept and experimental data,a kinetic model fitting for the gas-solid phase reduction of pellets in tubular reactors(blast furnace,BF) was built up,and the equations of reduction reaction rate were given for pellets.A series of reduction experiments of pellets were carried out to verify the model.As a result,the experimental data and calculated result were fitted well.Therefore,this model can well describe the gas-solid phase reduction process and calculate the reduction reaction rate of pellets.Besides,it can give a better explanation that the reduction reaction rate(reducibility) of MgO-fluxed pellets is better than that of traditional acidic pellets in BF.
As a main charging form of BF (blast furnace), pellets play an important role in blast furnace process. However, comparing with sinters, pellets have many disadvantages, such as reduction swelling, low softening and melting temperature and so on. Therefore, the flux pellets have been applied in blast furnace widely, especially MgO containing pellets. The light burned magnesite is applied as MgO containing additive in pellet production. The characters of light burned magnesite are explored. Meanwhile, the effects of it on low-temperature metallurgical properties are investigated such as low-temperature reduction degradation index (RDI), compressive strength (CS) and the reduction swelling index (RSI). The light burned magnesite calcined at 850 ℃ manifests better grindability, larger specific surface area, and higher hydration activity. It is found that the addition of light burned magnesite can improve low-temperature metallurgical properties (RDI, RSI) of the pellets. With the increase of light burned magnesite in pellets, the RSI and RDI decrease gradually; when the proportion of light burned magnesite does not exceed 2.0% in pellets, the CS decreases slightly, but it still surpasses 2 689 N, which can still meet the demand of BF.