采用硅烷偶联剂表面处理的氧化石墨烯(GO)与氰酸酯树脂(CE)/超支化聚硅氧烷(HBPSi)共混制备了CE/HBPSi/GO复合材料,研究了GO含量对复合材料力学性能、介电性能、热稳定性和吸水率的影响。结果表明,添加适量GO可以有效提高CE/HBPSi的韧性和强度,还可以改善其介电性能、热稳定性和耐湿性。当GO的质量分数为0.8%时,CE/HBPSi/GO复合材料的冲击强度和弯曲强度达到最大值,分别为15.1 k J/m^2和131.6 MPa,并且该体系的介电常数、介电损耗角正切和吸水率均低于CE/HBPSi体系,热稳定性优于CE/HBPSi体系。
Carboxymethyl cellulose sodium(CMC)/multi-walled carbon nanotube(MWCNT) composite was prepared by dissolving CMC with ionic liquid as solvent.The microstructure and electrochemical properties of CMC/MWCNTs were studied using field emission scanning electron microscopy(FE-SEM),high-resolution transmission electron microscopy(HR-TEM),X-ray diffraction(XRD) system and electrochemical workstation.The experimental results indicated that the CMC dissolved with ionic liquid could be uniformly enwrapped on the surface of MWCNTs,and the coating thickness of CMC was about 5.4 nm.There are obvious oxidation peaks in the cyclic voltammograms curves of glassy carbon electrode coated with a CMC/MWCNT composite in H2O2 phosphate buffer solution.The MWCNT content and ultrasonic time strongly affected the dispersivity and electrochemical property of CMC/MWCNT composite.While the MWCNT content and ultrasonic processing time was 2 wt% and 2 h respectively,CMC/MWCNT composite exhibited excellent electrocatalytic activity.
