您的位置: 专家智库 > >

广东省自然科学基金(9451063101002082)

作品数:7 被引量:22H指数:3
相关作者:汝强赵灵智胡社军田琴赖新方更多>>
相关机构:华南师范大学广东技术师范学院五邑大学更多>>
发文基金:广东省自然科学基金国家自然科学基金中国博士后科学基金更多>>
相关领域:电气工程电子电信理学化学工程更多>>

文献类型

  • 7篇中文期刊文章

领域

  • 3篇电子电信
  • 3篇电气工程
  • 1篇化学工程
  • 1篇理学

主题

  • 4篇电池
  • 4篇锂离子
  • 4篇锂离子电池
  • 4篇离子
  • 4篇离子电池
  • 3篇负极
  • 2篇第一性原理
  • 2篇溅射
  • 2篇磁控
  • 2篇磁控溅射
  • 2篇SB
  • 1篇第一性原理研...
  • 1篇电池负极
  • 1篇电子结构
  • 1篇真空
  • 1篇真空退火
  • 1篇射频磁控
  • 1篇射频磁控溅射
  • 1篇退火
  • 1篇子结构

机构

  • 4篇华南师范大学
  • 1篇广东技术师范...
  • 1篇五邑大学

作者

  • 4篇赵灵智
  • 4篇汝强
  • 3篇胡社军
  • 2篇田琴
  • 1篇何苗
  • 1篇赖新方

传媒

  • 3篇Scienc...
  • 1篇稀有金属材料...
  • 1篇物理学报
  • 1篇金属热处理
  • 1篇电源技术

年份

  • 5篇2011
  • 2篇2010
7 条 记 录,以下是 1-7
排序方式:
LixFePO4(x=0.0,0.75,1.0)电子结构与弹性性质的第一性原理研究被引量:11
2011年
采用基于密度泛函理论的第一性原理研究方法,计算了不同嵌锂态LixFePO4(x=0,0.75,1.0)的电子结构.对于橄榄石型LixFePO4正极材料,虽然Fe3d电子在费米能级附近相互交错,但由于受晶体场作用的限制,并不能真正成为自由电子,Fe3d电子对体系的导电性没有很大贡献,而Fe—O键在低能成键区形成p-d杂化的局域态共价键对稳定合金骨架具有重要作用.随着锂离子的脱出,体系表现出较强的共价键特征,LixFePO4中,共价键结合的强弱次序为P—O>Fe—O>Li—O.由弹性行为的计算结果可知,LixFePO4体系表现出脆性材料的特征,嵌锂态LixFePO4(x=1.0,0.75)比完全脱锂态的FePO4有更大的平均价键强度.
汝强胡社军赵灵智
关键词:锂离子电池LIFEPO4电子结构
真空退火对Sn负极材料结构与循环性能的影响被引量:1
2010年
用SEM、XRD、ICP、恒电流充放电方法对真空退火前后磁控溅射制备的锂离子电池用Sn负极薄膜材料的形貌、结构及循环性能进行研究。结果表明,经过200℃×8 h真空退火后,薄膜颗粒细化且均匀分布,薄膜中还出现了Cu6Sn5和Cu3Sn合金相的特征峰,改善了膜基结合力。相对于纯Sn电极,热处理后样品的首次放电容量和首次库仑效率均略有下降,分别为709 mAh/g和67%;从第2次到30次循环的容量保持率为87%,库仑效率维持在94%-99%,均优于纯Sn电极。
赵灵智胡社军汝强何苗
关键词:锂离子电池负极真空退火磁控溅射
溅射时间对Sb薄膜负极材料循环性能的影响被引量:5
2010年
采用射频磁控溅射法在300W功率下分别镀膜15、30、45min,制备了三种锂离子电池用Sb薄膜负极材料。通过XRD、SEM、ICP、恒电流充放电对三种薄膜材料的结构、形貌及循环性能等进行了表征。实验结果表明,当溅射时间为30min时,Sb薄膜电极具有最好的循环性能,首次嵌锂容量高达640mAh/g,20次循环后容量维持在323mAh/g,容量保持率为51%。
赖新方赵灵智汝强田琴
关键词:锂离子电池负极射频磁控溅射
Surface plasmon interference pattern on the surface of a silver-clad planar waveguide as a sub-micron lithography tool被引量:3
2011年
A new sub-micron photolithography tool has been realized by utilizing the interference of surface plasmon waves(SPWs) on the near surface of a silver(Ag)-clad ultraviolet(UV) planar waveguide.A laser beam with a wavelength of 325 nm was incident into the waveguide core,and suffered a series of total internal reflections on the interfaces between the waveguide core and the cladding layers.The incident light and the reflected light induced two beams of SPWs traveling in contrary directions,which interfered with each other and formed a standing wave as a sub-micron photolithography tool.A near-field scanning optical microscope(NSOM) was employed to measure the intensity distribution of the stationary wave field of the near surface of the Ag layer of the waveguide,anastomosed with theoretical values acquired by use of finite difference time domain(FDTD) simulations.And with this sub-micron photolithography tool a SMG with a period of 79.3 nm,in good agreement with the theoretical value of 80.1 nm,was inscribed on the surface of a self-processing hybrid SiO2/ZrO2 solgel film for the first time.
ZHU QiuXiangHU CanDongWANG WenJieHE MiaoZHOU JunZHAO LingZhiPENG ZhiXiangLI ShuTiZHU NingZHANG Yong
关键词:SOLGEL
Novel sol-gel material for fabrication of a long period waveguide grating filter as a precise thermometer被引量:2
2011年
A new kind of organic-inorganic hybrid HfO2/SiO2 sol-gel material with a large thermo-optic coefficient and a wide linear tunable temperature range has been developed for fabrication of a long period waveguide grating (LPWG) filter, whose parameters were optimized and designed by using finite difference time domain (FDTD) simulations. The LPWG filter, a periodic rectangle-corrugated grating structure, was easily fabricated with soft-lithography technique. At a temperature range from 19~C to 70~C, the fabricated LPWG filter element demonstrated a high temperature sensitivity of about 6.5 nm/~C and a wide linear tunable temperature range of 51℃, so that it can be used as a precise thermometer. Our results are useful for the designs of LPWG filters for the implementation of a wide range of thermo-optic functions.
WANG XinLI XiaoChanZHANG TaoHU CanDongZHU QiuXiangCHEN SiHaiLI YunXU JiaHE MiaoNIU QiaoLiZHAO LingZhiLI ShuTiZHANG Yong
关键词:SOFT-LITHOGRAPHY
Sb薄膜嵌脱Li性质的平面波赝势法计算与实验研究被引量:1
2011年
采用基于密度泛函理论的第一性原理超软赝势平面波方法计算了Li-Sb合金的嵌锂性能,得到合金的嵌锂形成能、嵌锂电位、理论比容量、体积膨胀率和能带结构等。并用恒流充放电和循环伏安法实测了薄膜电极的充放电性,Sb电极在循环时,表现出平稳的0.8V嵌锂电压平台,其电位与理论计算较吻合。富锂态LixSb(2
汝强赵灵智田琴胡社军
关键词:第一性原理锂离子电池负极
Enhancement of light output powers of GaN-based light emitting diodes with textured indium tin oxide transparent layer by using corrosive liquid
2011年
In order to promote the light output powers of GaN-based light emitting diodes (LEDs), two kinds of novel corrosive liquidshave been developed in this paper to roughen the surface of the indium tin oxide (ITO) current spreading layer of LEDs. As aresult, the textured transparent ITO layer greatly enhanced the external quantum efficiency of the LEDs. Provided that a wafersample was dipped in a kind of corrosive liquid developed by us for only about 60 s, the light output powers of the LEDs canbe promoted by 24.7%, compared with conventional GaN-based LEDs. It is obvious that the presented method is simple, rapidand cost-effective.
LI YunLI XiaoChanZHANG TaoHE AnHeHU CanDongWANG XinHE MiaoZHANG YongNIU QiaoLiZHAO LingZhiLI ShuTiCHEN XianWen
共1页<1>
聚类工具0