以天然鳞片石墨为原料,利用电泳插层法制备出具有适当膨胀体积的微膨石墨,石墨的结构缺陷增多,具有较大的比表面积和增大的石墨层间距。微膨石墨的可逆容量可以达到521 m Ah/g;在0.2 C倍率循环充放电30次容量最佳可保持在99%以上,在1.0 C循环50次其容量可稳定在188 m Ah/g,且表现出良好的倍率性能。微膨石墨电化学性能的改善得益于其具有适当的比表面积及内部结构的改变。交流阻抗测试显示微膨石墨的SEI膜阻抗和电荷传递阻抗小于鳞片石墨,具有良好的电化学活性。
Many hybrid electrodes for supercapacitors(SCs)are a reckless combination without proper structural design that keeps them from fulfilling their potential.Herein,we design a reduced graphene oxide/poly(3,4-ethylenedioxythiophene)/polyaniline(RGO/PEDOT/PANI)hybrid with hierarchical and porous structure for high-performance SCs,where components fully harness their advantages,forming an interconnected and conductive framework with substantial reactive sites.Thus,this hybrid achieves a high capacitance of 535 F g^−1 along with good rate capability and cyclability.The planar SC based on this hybrid deliver an energy density of 26.89 Wh kg^−1 at a power density of 800 W kg^−1.The linear SC developed via modifying a cotton yarn with the hybrid exhibits good flexibility and structural stability,which operates normally after arbitrary deformations.This work provides a beneficial reference for developing SCs.
