Confined impinging jet reactor(CIJR)offers advantages for chemical rapid processes and has become an important new reactor used in the chemical industry.The micromixing efficiency in a T-shaped CIJR for two tubes of inner diameter of 3 mm was studied by using a parallel competing iodide–iodate reaction as the working system.In this work,the effects of different operating conditions,such as impinging velocity and acid concentration,on segregation index were investigated.In addition,the effects of the inner nozzles diameter and the distance L between the jet axis and the top wall of the mixing chamber on the micromixing efficiency were also considered.It is concluded that the best range of L in this CIJR is 6.5–12.5 mm.Based on the incorporation model,the estimated minimum micromixing time tmof CIJR approximately equals to 2×10-4s.These experimental results indicate clearly that CIJR possesses a much better micromixing performance compared with the conventional stirred tank(micromixing time of 2×10-3to 2×10-2s).Hence,it can be envisioned that CIJR has more promising applications in various industrial processes.
The parallel-competing iodide-iodate reaction scheme was used to study the micromixing performance in a multi-phase stirred tank of 0.3 m diameter.The impeller combination consisted of a half elliptical blade disk turbine below two down-pimping wide-blade hydrofoils,identified as HEDT + 2WH_D.Nitrogen and glass beads of100 μm diameter and density 2500 kg-m^(-3) were used as the dispersed phases.The micromixing could be improved by sparging gas because of its additional potential energy.Also,micromixing could be improved by the solid particles with high kinetic energy near the impeller tip.In a gas-solid-liquid system,the gas-liquid film vibration with damping,due to the frequent collisions between the bubbles and particles,led to the decrease of the turbulence level in the liquid and caused eventually the deterioration of the micromixing.A Damping Film Dissipation model is formulated to shed light on the above micromixing performances.At last,the micromixing time t_m according to the incorporation model varied from 1.9 ms to 6.7 ms in our experiments.
The toxic gases,such as CO and NO,are highly dangerous to human health and even cause the death of person and animals in a tiny amount.Therefore,it is very necessary to develop the toxic gas sensors that can instantly monitor these gases.In this work,we have used the first-principles calculations to investigate adsorption of gases on defective graphene nanosheets to seek a suitable material for CO sensing.Result indicates that the vancancy graphene can not selectivly sense CO from air,because O2 in air would disturb the sensing signals of graphene for CO,while the nitrogen-doped graphene is an excellent candidate for selectivly sensing CO from air,because only CO can be chemisorbed on the pyridinic-like N-doped graphene accompanying with a large charge transfer,which can serve as a useful electronic signal for CO sensing.Even in the environment with NO,the N-doped graphene can also detect CO selectively.Therefore,the N-doped graphene is an excellent material for selectively sensing CO,which provides useful information for the design and fabrication of the CO sensors.
Solubility data of carbon dioxide （CO2） （1） in methanol （2）, 1-octyl-3-methylimidazolium bis（trifluoro- methylsulfonyl）imide （[omim]＋[TfzN]-） （3）, and their mixtures （w3 = 0.2, 0.5, and 0.8） at temperatures 313.2 and 333.2 K and pressures up to 7.0 MPa were measured by a high-pressure view-cell technique. The solubility of CO2 in methanol （w3 = 0）, [omim]＋[Tf2N]- （w3 = 1.0） and their mixtures follows the order of （w3 = 0）〈（w3 = 0.2）〈 （w3 = 0.5）〈（w3 = 0.8）〈（w3 = 1.0） at the same temperature and pressure, while the magnitude of Henry＇s constants follows the reverse order at a given temperature, which is consistent with the COSMO-RS （conductor-like screen- ing for real solvents） calculation. The solubility data of CO2 in methanol and [omim]~[Tf2N]- are correlated with the Peng-Robinson equation of state, and the solubility of CO2 in the mixtures of methanol and [omim]＋[TfzN] can be well predicted based on the mole fraction average of methanol and [omim]＋[Tf2N] over the solubility of CO2 in pure methanol and [omim]＋[Tf2N] . The mixtures of methanol and [omim]＋[Tf2N]- may be used as physical solvents for capturing CO2 with high partial pressures since they combine the advantages of organic solvents and ionic liquids.
This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five different channel shapes (circle, regular triangle, rectangle, square and hexagon), was investigated to make a comprehensive comparison of their pressure drop, heat transfer Nu number, mass transfer Sh number and N2O conversion. It was found that monolith catalysts have a much lower pressure drop than that of traditional packed bed, and for monolith catalysts with different channel shapes, pressure drop decreases in the order of regular triangle > rectangle > square > hexagon > circle. The order of Nu is in regular triangle > rectangle ≈ square > hexagon > circle, similar to that of Sh. N2O conversion follows the order of regular triangle > rectangular ≈ square ≈ circle > hexagon. The results indicate that chemical reaction including internal diffusion is the controlling step in the selective catalytic reduction of N2O removal with CO. In addition, channel size and gas velocity also have influence on N2O conversion and pressure drop.
Orderly mesoporous CuFe2O4spinel-type mixed oxide with high specific surface area was prepared successfully by a hard-template method in which KIT-6mesoporous silica was selected as the hard template.The KIT-6 hard template and CuFe2O4samples were characterized by X-ray diffraction,X-ray photoelectron spectroscopy,X-ray fluorescence,transmission electron microscopy,scanning electron microscopy,nitrogen physisorption,and hydrogen-temperature programmed reduction.The KIT-6 hard template had perfect crystallization and ordered mesoporous structure with a probable pore distribution of about 9.1 nm,large enough to be filled by the spinel precursor.The mesoporous CuFe2O4spinel oxide synthesized inside the KIT-6 mesopores had a relatively small pore size(4.3 nm),orderly arrangement,and high specific area(194 m2/g).The catalytic activity of the mesoporous CuFe2O4was tested for the selective oxidation of ammonia to nitrogen.The conversion of ammonia reached nearly 100%at 300°C with a nitrogen selectivity as high as 96%.The nitrogen selectivity remained high with increasing temperature and even maintained a value of80%at 600°C.
