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国家自然科学基金(U1037601)

作品数:12 被引量:22H指数:4
相关作者:胡劲韩庆胡壮麒孙晓峰王亚飞更多>>
相关机构:昆明理工大学中国科学院中国科学院金属研究所更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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12 条 记 录,以下是 1-10
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气相沉积铼的前驱体二聚(二乙酰丙酮合铼酰)的合成与表征
2013年
合成了一种新型化学气相沉积铼的前驱体——二聚(二乙酰丙酮合铼酰);采用红外光谱仪、紫外光谱仪、质谱仪及电感耦合等离子体发射光谱仪等对其进行了结构表征.结果表明,乙酰丙酮与铼发生配位反应并成环,从而形成目标前驱体.
王薇胡劲王玉天唐华赵娜
关键词:化学气相沉积前驱体乙酰丙酮
Progress of phase-field investigations of γrafting in nickel-base single-crystal superalloys被引量:3
2014年
With the development of nucleation theory,the calculation of phase diagrams(CALPHAD)method and microscopic elasto-plasticity mechanics,it is possible to apply the phase-field method to simulate the γrafting behavior of nickel-base single-crystal superalloys under the conditions of heat treatment,fatigue and creep testing.Based on the experimental progress in γrafting behavior and in combination with the microstructural simulation of the precipitation and rafting of c0phase,this paper reviews the phase-field investigation of γrafting in nickel–base single-crystal superalloys.
Yan ZhaoHongyu ZhangHua WeiQi ZhengTao JinXiaofeng Sun
关键词:镍基单晶高温合金相场法弹塑性力学
热处理对NTS-09C超高温合金组织及性能影响
研究了热处理对NTS-09C超高温合金组织及性能的影响,铸态合金和经热处理后的合金主要由Nbss、γ-Nb5Si3及β-Nb5Si3组成。经热处理后,Nb5Si3相逐渐溶解或破碎成小块并发生球化,其形貌由针状转变为颗粒状...
杨彦红于金江娄建新孙晓峰管恒荣胡壮麒聂全新颉维平王锦辉
关键词:超高温合金
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Microstructure of Carbides at Grain Boundaries in Nickel Based Superalloys被引量:4
2012年
It is well known that carbides at grain boundaries play an important role in affecting mechanical properties of nickel based superalloys. In order to deeply understand the relationship between grain boundary structures and properties, in this work, we have investigated the microstructure of grain boundaries with different misorientation angles in bicrystals of nickel based superalloys. It is found that the bicrystals with smaller misorientation angles contain denser M 23 C 6 but sparse MC particles at grain boundaries, and this kind of bicrystals presents longer stress rupture lives. It was observed that MC carbides were decorated by M 23 C 6 and M 6 C particles at grain boundaries. The formation of these carbide particles, therefore, is likely due to the local fluctuation of chemical composition around MC carbides. In addition, the orientation relationships between MC carbides and γ/γ matrix were also determined.
Xiaoming DongXiaoli ZhangKui DuYizhou ZhouTao JinHengqiang Ye
关键词:镍基高温合金晶界碳化物微观结构M23C6MC碳化物
汽车氧传感器用电极材料的研究被引量:4
2013年
汽车氧传感器根据工作原理可分为3类:(1)浓差型;(2)极限电流型;(3)氧化物半导体型。汽车氧传感器是电喷发动机控制系统中关键的传感部件,电极是氧传感器中最重要的组成部分。目前,低温(600℃)下以银电极为主;高温(600~900℃)下则以铂电极为主,但因其价格昂贵,金属陶瓷复合电极正逐渐代替铂电极;一些半导体金属氧化物电极也表现出一定的应用前景。
韩庆胡劲蒋丹宇
关键词:氧传感器电极
氧化锆氧传感器多孔Pt/YSZ电极的制备与表征被引量:1
2013年
在氧化锆基片上丝网印刷Pt电极浆料,并在不同的温度下烧结制成电极。用扫描电镜表征烧结后多孔Pt/YSZ电极的微观形貌,并用电化学阻抗谱(EIS)研究多孔Pt/YSZ电极的电学性能。结果表明:烧结温度对电极微观形貌的影响很大,多孔Pt/YSZ电极有优良的催化性能。
韩庆冯涛夏金峰胡劲
关键词:YSZ复合电极烧结温度微观形貌多孔
Ru对单晶高温合金中γ′相析出行为和演化的影响(英文)被引量:4
2013年
采用扫描电镜、3D原子探针、示差热分析等方法研究了合金元素Ru对单晶高温合金中γ′相的析出和演化过程的影响。研究结果表明:γ′的溶解温度随着Ru含量的增加而逐渐降低。铸态下以及固溶处理和时效处理后,γ′相尺寸都随着Ru含量的增加而减小。Ru的加入加快了γ′相的长大和粗化速率,Ru主要分布在γ′基体中。Ru的加入使更多的Mo和Re等元素向γ′相分配,导致错配度的绝对值增大,同时加快γ′相的形筏速率。
刘丽荣金涛刘金来孙晓峰胡壮麒
关键词:单晶高温合金错配度
超细硼化锆粉体纯化工艺探究
2017年
探究了超细ZrB_2粉体化学提纯、热处理等纯化工艺过程中的影响因素。并采用热重-差热分析仪、X射线衍射仪、扫描电镜、透射电镜和X射线荧光光谱分析仪对ZrB_2粉体及热处理后的水洗产物进行表征和分析。结果表明:B_2O_3易溶于热水生成硼酸溶液,为了有效地除去B_2O_3,需经过热水反复洗涤、过滤;随着热处理温度增加,粉体中的C杂质逐渐氧化挥发,但当热处理温度升至700℃时,产物中的ZrB_2被氧化生成ZrO_2,致使产物迅速增重;热处理温度650℃和热处理时间80 min为最佳热处理除杂工艺,此时产物中残留的碳基本全部被除去,但是产物中氧含量较高,后期研究建议选择在惰性气氛中进行。
王亚飞张帆李军段云彪王开军张维钧胡劲
关键词:硼化锆纯化工艺
Dendritic Growth Pattern and Dendritic Network Distortion in the Platform of a Ni-based Superalloy被引量:4
2014年
The pattern of dendritic growth and distortion of dendritic network in the platform have been investigated by one mold casting with different platform length during directional solidification. As the platform length elongates, the symmetry of dendritic growth along left and right edges gradually worsens in platform base. While the platform length reaches 14 mm, the distortion of dendritic network is first observed in outward platform. It is found that the distortion of dendritic network along platform inside is more serious than that along platform edges. Both[001] deviation and accumulated misorientation along platform inside, up to 9 and 16.3, respectively, are far greater than those along lefte outwarde right edges. The deformation of dendritic network in a platform may be caused by the asymmetry of the solidification front at the mush zone.
Xiaoli ZhangYizhou ZhouYanyun HanTao JinXiaofeng Sun
关键词:枝晶生长镍基高温合金树突定向凝固
Transient liquid-phase bonding of superalloy K465 using a Ni-Cr-Fe-B-Si amorphous interlayer alloy
2020年
A kind of Ni-Cr-Fe-B-Si system amorphous alloy was used as interlayer in transient liquid-phase bonding(TLP bonding)of polycrystalline superalloy K465.The bonding behavior,microstructure feature and the tensile properties of the joints were investigated.There are B-rich phase and Si-rich phase formed in the center of the seam after bonding at 1210℃for 30 min.The isothermal solidification is complete after bonding at 1210℃for 4 h.The relationship of the average width of the remnant eutectic zone and bonding time at 1210℃is nonlinear.The tensile strength of the bonded joint at room temperature and 900℃is comparable to that of K465 alloy.
Ji-De LiuBo LiYuan SunTao JinXiao-Feng SunZhuang-Qi Hu
关键词:SUPERALLOY
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