Using the Hamiltonian function method, this paper proposes a family of robust adaptive excitation con- trollers for synchronous generators with steam valve control. First, a parameterization method of robust adaptive controllers is investigated for dissipative Hamiltonian systems. This method avoids solving Hamilton-Jacobi-Issacs inequalities. The parameters in the family of controllers thus obtained are determined by a locally positive semidefinite function, which has only 2n independent variables, twice as many as the one used to characterize the state feedback. Then, with the parame- terization method and the structural properties of dissipative Hamiltonian systems, a family of robust adaptive excitation controllers is designed for synchronous generators with steam valve control, disturbances and unknown parameters. Simu- lations illustrate the effectiveness and feasibility of the excitation control strategy proposed in the paper.