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作品数:3 被引量:15H指数:2
相关作者:殷鹏刚孙都郭林更多>>
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Porous cobalt oxide nanowires: Notable improved gas sensing performances被引量:4
2012年
The porous Co3O4 nanowires have been successfully synthesized via modified template method. A possible growth mechanism governing the formation of such 1D nanowires is proposed. The as-prepared products have been characterized by X-ray Powder Diffraction (XRD), Extended X-ray Absorption Fine-structure (EXAFS), High-resolution Transmission Electron Microscopy (HRTEM) and N2 adsorption/desorption analysis. Our systematic studies have revealed that the porous Co3O4 nanowires show excellent gas sensing performances, which demonstrate the potential application of the 1D nanostructured Co3O4 in the detection of the ethanol gas as a sensor material. The improved performances are owing to its large specific surface area and porous morphology.
MA MaiXiaPAN ZhiYunGUO LinLI JingHongWU ZiYuYANG ShiHe
关键词:钴氧化物扩展X射线吸收精细结构高分辨透射电子显微镜X射线粉末衍射
纳米多级结构枣核型多孔氧化亚铜的合成及拉曼性质被引量:11
2011年
通过简单温和的水相还原反应,在表面活性剂十二烷基苯磺酸钠(SDBS)的协同下合成了亚微米级枣核型多孔氧化亚铜纳米多级结构.通过改变盐酸的加入量可以实现纳米粒子尺寸在300-900nm范围可调.X射线衍射(XRD)和透射电子显微镜(TEM)分析表明,亚微米粒子由小于10nm的晶粒构成.基于实验结果,我们提出生长-刻蚀竞争生长模型来解释枣核型空心多孔结构的形成机制,同时说明了尺寸调节机理.利用激光拉曼光谱仪研究了样品的光学性质,与相似尺寸的亚微米实心多面体的拉曼响应信号对比发现,枣核型空心多孔结构的拉曼光谱表现出新颖的特性.这些结果补充了氧化亚铜的拉曼光谱样本,对文物表面颜料的无损拉曼检测具有一定的指导意义.
孙都殷鹏刚郭林
关键词:纳米材料十二烷基苯磺酸钠氧化亚铜拉曼光谱
Magnetic Co_3O_4 nanowires,preparation and properties
2012年
The Co3O4 nanowires have been successfully synthesized via modified template method.The as-prepared products have been characterized by EDS,TEM and HRTEM analysis.The magnetic behavior of it is investigated by a magnetic property measurement system.The nanowires exhibit some novel magnetic properties,which are different from its bulk material.The temperature dependence curves of magnetization in zero-field-cooling and field-cooling exhibit two peaks of antiferromagnetic at blocking temperature of~23 K and~31 K,respectively.The field dependent M(H) curves of the Co_3O_4 nanowires at T = 5 and 300 K both exhibit PM properties.Moreover,the diameter of nanowires is hence determined according to the finite size effect as approximately 7-11 nm,in consistent with the characterizations by HRTEM.
Mai Xia MaWei Meng ChenLin GuoJing Hong LiChin Ping ChenShi He Yang
关键词:NANOSTRUCTURESOXIDES
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