Hierachically porous (HP) CuO/α-Fe2O3/SiO2 composite material was fabricated by sol-gel method and multi-hydrothermal processes using HP-SiO2 as support.The resulting material was characterized by N2 adsorption-desorption,X-ray diffraction and scanning electron microscopy.The as-prepared CuO/Fe2O3/HP-SiO2 sample,with α-Fe2O3 and CuO nanocrystals,possessed a co-continuous skeleton,through-macroporous and mesoporous structure.Its catalytic behavior for CO and o-DCB oxidation was investigated.The result showed that CuO/Fe2O3/HP-SiO2 catalyst exhibited high catalytic activity for both CO and o-DCB oxidation,indicating its potential application in combined abatement of CO and chlorinated volatile organic compounds.
The distribution of seventeen gaseous and particle-bound 2,3,7,8-substituted chlorinated PCDD/Fs in the flue gas of different windboxes of the sintering machine was analyzed.The influence of temperature change on the PCDD/Fs emission from the sintering process and the formation mechanism of PCDD/Fs were discussed.The result has shown that among the seventeen gaseous and particle-bound PCDD/Fs in the flue gas of different windboxes,furans occupied the major place.The proportion of the gaseous PCDD/Fs in most windboxes is from 40% to 60%.The change tendencies of the concentration of both the gaseous and particle-bound PCDD/Fs were similar,with a higher level at the end of the sintering bed.The PCDD/Fs concentration's change tendency in the windbox was very consistent with the change of temperature of the flue gas in the windboxes.More than 60% PCDD/Fs of the total PCDD/Fs emission amount was emitted at the end of the sintering bed.Only this part of the waste gas accounted for 12% of the total waste gas volume.
The phase transition of 2,5-distyrylpyrazine (DSP) adsorbed on Au(111) substrate was studied as a function of the substrate potential in 0.1 M HClO 4 , using an in situ scanning tunneling microscope (STM). Depending on the applied electric field, DSP formed three distinctly different, two-dimensionally (2D) ordered, supramolecular nanostructures on the Au(111) surface. In the potential range of 0.55 V < E < 0.75 V, the DSP molecules formed a close-packed stripe pattern with the adlayer structure 1 3 . 8 6 When the potential was reduced to 0.45 V < E < 0.55 V, a ridge-like pattern built from dimer subunits was observed, with the adlayer structure 4 5 . 12 4 Further decreasing in the electrode potential to 0.2 V < E < 0.45 V caused the appearance of a herringbone-like pattern consisting of dimer subunits, with the adlayer structure 9 0 . 3 9 The potential-induced phase transitions revealed the structure-determining role of substrate-adsorbate coordination and intermolecular interaction in forming the distinct 2D adlayer motifs.
