Pseudo-first order reaction rate constants of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo (F_(15)CMn(V)-oxo),5,15-bis(pentafluorophenyl)-10-(phenyl)corrole Mn(V)-oxo(F_(10)CMn(V)-oxo),5,15- bis(phenyl)-10-(pentafluorophenyl)corrole Mn(V)-oxo(F_5CMn(V)-oxo) and 5,10,15-tris(phenyl)corrole Mn(V)-oxo(F_0CMn(V)-oxo) with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy.The results indicated that the oxygen atom transfer pathway between Mn(V)-oxo corrole and alkene is solvent-dependent.
Lan YuQi WangLu DaiWei-Ying LiRong ChenMian HR MahmoodHai-Yang LiuChi-Kwong Chang