The calculating model for the packing degree of spherical particles system was modified. The grain grading model of cement-based materials was established and could be applied in the global grading system as well as in the nano-fiber reinforced system. According to the grain grading model, two kinds of mortar were designed by using the global grain materials and nano-fiber materials such as fly ash, silica fume and NR powder. In this paper, the densities of two above systems cured for 90d were tested and the relationship of deleterious porosity and the total porosity of hardened mortar was discussed. Research results show that nano-fiber material such as NR powder can increase the density of cement-based materials. The relationship of deleterious porosity and the total porosity of hardened mortar accords with logarithmic curve. The deleterious porosity and the rationality of the grading can be roughly predicted through calculating the packing degree by the grain grading model of cement-based materials.
The prediction model for inhibition effect of reinforced concrete was presented based on the Magge＇s model when the concrete surface was brushed with nitrite solution. The influence of the amount of nitrite solution on inhibiting duration was also discussed through a simulation analysis when the amount of solution were 250 g/m^2, 500 g/m^2, 1000 g/m^2 and 1500 g/m^2, respectively. The experimental results confirm that nitrite ion can diffuse well in concrete to reach an effective mol ratio from the surface of the concrete to the surface of the reinforcement, and has an effective protection for the bars against corrosion. The higher the amount of solution, the better it will accelerate getting the threshold value of mol ratio on the surface of rebar, and retarding the time for loosing the effective threshold value of mol ratio. It helps to increase the tendency of inhibiting duration and prolong the life of reinforced concrete. The nitrite solution amount is used to predict the corrosion inhibiting duration of concrete that contains chloride salt.
