It is important to accurately predict the flow mode especially intertube falling-film mode of absorbent for its great impact on the heat and mass transfer in a horizontal tube absorber. In this paper, a test facility used to study falling-film outside horizontal tubes was built, and experiments were conducted to explore the intertube mode transi- tions with water-calcium chloride (CaC12/water) solution in quiescent surroundings. The correlations which are more suitable for predicting CaC1jwater solution intertube mode transitions were developed. In general, the transitional Re will decrease with the solution concentration increasing, and its effects increase with the transitions from droplet mode to sheet mode. Hysteresis exists in all the mode transitions, and it is more obvious for low concentration solutions. The results may be an important support for modeling, designing and operating of CaC12/water falling-film absorber.