Inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectroscopy, hydride generation-atomic fluorescence spectrometry, emission spectrometry, X fluorescence spectrometry, and X-ray diffraction were employed to study the geochemistry and mineralogy of coal gangues from Nos. 2, 3, and 8 coal seams of the Du'erping coal mine, Xishan coalfield, Taiyuan, Shanxi Province. The study revealed that compared with the sedimentary cover, upper continent crust, Carboniferous-Permian coal from North China, as well as most coal in China, coal gangues from Nos. 2 and 3 coal seams are rich in Li, Be, Sc, Cr, Cu, Ga, Ba, Th, Nb, Cd, Pb, Ta and rare-earth elements, and coal gangues from No. 8 coal seam are rich in Li, Sc, V, Cr, Ga, U, and rare-earth elements. Compared with the Carboniferous-Permian coal from North China and most coal in China, coal gangues from Nos. 2, 3 and 8 seams are rich in Rb, V, Cs and Sr. Therefore, The Du'erping coal gangues in the Xishan coalfield are rich in most hazardous trace elements and rare-earth elements, wherein the contents of Ga and Li reach the industrial grade and have significance for industrial utilization. On the whole, coal gangues of the Shanxi Formation from the Permian are rich in more trace elements than those of the Carboniferous Taiyuan Formation. The distributions of REE show obviously dipping rightwards with negative Eu anomalies. The contents of rare-earth elements in the three seams are quite different. All of the above indicate that the source of the rare-earth elements is terrigenous debris. Minerals in No. 2 seam identified by X-ray diffraction mainly include quartz, kaolinite, in addition to calcite, pyrite, apatite, epidote, and epsomite. No. 3 seam mainly contains quartz, kaolinite, in addition to a small amount of sodium feldspar, calcium nitrate, iron ore, gypsum, and vivianite. No. 8 seam mainly contains kaolinite, dickite, quartz, illite, and a small amount of hematite and U. The correlations between major elements and trace elemen
在对浙江省某铜矿进行瞬变电磁勘查时,由于感应激发极化效应的影响,造成瞬变电磁晚期测道的数据发生倒转。采用常规的瞬变电磁数据处理方法难以处理,造成晚期测道数据不可用,影响TEM的探测深度及精度。针对这个情况,采用Cole.Cole模型分析了均匀半空问模型中直流电阻率、充电率、时间常数以及频率相关系数对磁性源瞬变电磁响应的影响规律。利用奇异值分解法(The Singular Value Decomposition,简称SVD)对实测TEM数据进行分析及反演,并且从瞬变电磁响应数据中分离出勘探区瞬变电磁测量数据Cole—Cole模型的各参数,将分离出来的参数用于探测结果的辅助解释。经过分析得出充电率和频率相关系数对瞬变电磁响应的影响较大,而直流电阻率和时间常数对其影响较小的结论。通过常规方法和奇异值分解法对实测数据分别进行处理,发现后者视电阻率断面图的异常更加突出,从而较准确的圈定了铜矿体地范围,此结论得到_『钻孔的验证,与实际地质情况吻合较好。
