Our recent studies of the crystal structures, phase transitions, and magnetic properties of intermetallic compounds RsM4 （R = rare earths; M = Si, Ge） are reviewed briefly. First, crystal structures, phase relationships, and magnetic prop- erties of several 5：4 compounds, including Nd5 Si4-xGex, Pr5 Si4_xGex, Gds-xLaxGe4, La5 Si4, and Gd5 Sn4, are presented. In particular, the canted spin structures as well as the magnetic phase transitions in PrsSi2Ge2 and PrsGe4 investigated by neutron powder diffractions and small-angle neutron scattering are reviewed. Second, the crystal structures and magnetic properties of the most studied compounds Gds（Si,Ge）4 are summarized. The focus is on the parent compound GdsGe4, which is an amazing material exhibiting magnetic anisotropy, angular dependent spin-flop transition, metastable magnetic response, Griffiths-like phase, thermal effect under pulsed fields, antiferromagnetic and ferromagnetic resonances, pro- nounced effects of impurities, and high-field induced magnetic transitions.
Glassy magnetic behavior and exchange bias phenomena are observed in single phase Mn3O4 nanoparticles.Dynamics scaling analysis of the ac susceptibility and the Henkel plot indicate that the observed glassy behavior at low temperature can be understood by taking into account the intrinsic behavior of the individual particles consisting of a ferrimagnetic（FIM） core and a spin-glass surface layer.Field-cooled magnetization hysteresis loops display both horizontal and vertical shifts.Dependence of the exchange bias field（HE） on the cooling field shows an almost undamped feature up to 70 kOe,indicating the stable exchange bias state in Mn3O4.HE increases as the particle size decreases due to the higher surface/volume ratio.The occurrence of the exchange bias can be attributed to the pinning effect of the frozen spin-glass surface layer upon the FIM core.
