This paper investigates the thermal pairwise entanglement of a three-qubit Heisenberg XXZ chain in the presence of the Dzyaioshinski-Moriya (DM) anisotropic antisymmetric interaction and quantum teleportation when using the Heisenberg chain as a channel. The entanglement dependences on the DM interaction and temperature are given in detail. It obtains the relation between the concurrence and average fidelity, and shows that the same concurrence can lead different average fidelities. Moreover, it finds the thermally entangled states which do not violate the Bell inequalities, and can still be used for quantum teleportation.