The complexes of [Ag2Pd2(μ-dppm)2(μ-S2CNC4H8)2(μ3-S2CNC4H8)2](SbF6)2·Et 2O (1) and [AgPd(S2CN C4H8)(μ-dppm)2](SbF6)·H2O (2)were synthesized and their single crystal structures were determined by X-ray diffraction. The complex 1 is monoclinic system, space group P21/c with a=1.14370(3)nm, b=1.39025(4)nm, c=2 .93579(8)nm, β=95.173(1)°, V=4.6490(2)nm3, Z=4, Dc=1.716g·cm-3, μ(MoKα)=16 82cm-1, F(000)=2384, Mr=2401.98, R=0.0662, wR=0.1302. The complex 2 is monoclin ic system, space group Cc with a=2.74136(6)nm, b=1.04317(2)nm, c=2.523990(10)nm, β=95.173(1)°, V=4.6490(2)nm3, Z=4, Dc=1.716g·cm-3, μ(MoKα)=1682cm-1, F(0 00)=2384, Mr=2401.98, R=0.0662, wR=0.1302. CCDC: 1, 213613; 2, 213612.