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国家自然科学基金(51171007)

作品数:3 被引量:2H指数:1
相关作者:姜鹤曾敏邹志宇唐瑞鹤刘晓芳更多>>
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发文基金:国家自然科学基金国家重点基础研究发展计划中央高校基本科研业务费专项资金更多>>
相关领域:化学工程一般工业技术金属学及工艺更多>>

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Local Structure Mediation and Photoluminescence of Ce^(3+)-and Eu^(3+)-Codoped YAG Nanophosphors被引量:2
2018年
Cerium and europium codoped yttrium aluminum garnet(YAG:Ce,Eu) nanophosphors were prepared by sol-gel method.We systematically explored the structure,composition,morphology and photoluminescence(PL) properties by using X-ray diffraction,scanning electron microscope,high resolution transmission electron microscope,energy dispersive spectrometer,photoluminescence emission and excitation spectra techniques,and focused on clarifying the change of local structure surrounding Ce^3+ ions by utilizing advanced quantitative ^27Al magic angle spinning nuclear magnetic resonance spectroscopy.The results show that the lattice constant slightly increases as the Ce^3+ and Eu^3+ ions incorporate,and the geometric distortion of local structure surrounding Ce^(3+) activator introduced by the incorporated Eu^(3+) coactivator causes the variation of crystal field,which results in red shift of Ce^3+ PL emitting in YAG:Ce,Eu nanophosphor.Furthermore,the YAG:Ce,Eu nanophosphors could exhibit several sharp and narrow ^5D0 → ^7FJ(J = 1-4) emissions of Eu^3+ ion besides the classic broad ^5d1 → ^4f(^2F(5/2),^2F(7/2)) emissions of Ce^3+ ion under near ultraviolet(UV) excitation.
何小武刘晓芳李建荣于荣海
电场辅助溶解法实现玻璃表面金纳米粒子的形貌控制
2012年
贵金属纳米粒子由于其非常独特的光学特性和表面活性,在光子学、催化和生物标识等方面都有非常重要的应用.采用离子溅射和后续热处理相结合的方法在玻璃表面形成了尺寸大约为60—80 nm的单分散的球形金纳米粒子.在适当的温度条件下,采用步进式增加的强直流电场,实现了金纳米粒子的电场辅助溶解过程.在玻璃表面的不同颜色区域,初始球形的金纳米粒子溶解成月蚀状形貌.结合不同颜色区域内金纳米粒子的表面等离子体共振吸收性质和扫描电镜照片,研究了实验条件对金纳米粒子性质的影响.结合电场辅助溶解实验过程中的电流-电压特性,分析了金纳米粒子在强直流电场辅助下溶解的物理过程:金粒子中动出的电子向阳极的隧穿过程作为开始,随后是金阳离子向玻璃基体中的传输过程和阴极提供的电子与带有正电荷的金粒子相结合的过程.详细讨论了电场辅助溶解法实现金纳米粒子形貌控制的物理机制.
邹志宇刘晓芳曾敏杨白于荣海姜鹤唐瑞鹤吴章奔
关键词:金纳米粒子表面等离子体共振电流-电压特性
Preparation of in-plane anisotropy Ni_(80)Co_(20)/Bi multifilms
2015年
A series of Au/[NiCo/Bi]x/Au (x = 2, 3) films were fabricated by pulsed laser deposition method. In order to induce the in-plane uniaxial magnetic anisotropy (IPUMA) of the multifilms, multiple layers and different oblique angles ranging from 0° to 30° for the substrate are applied during the deposition. The microstructures of the nanofilms were investigated by using X-ray diffraction (XRD) and transmission electronic microscope (TEM). And their magnetic properties were measured by an alternating gradient magnetometer. For the multicycle systems, using the method that with more periodic structures of NiCo/Bi film is easier for inducing IPUMA than the less or the samples located with various angles.
Hao-Zhe YangMin ZengXin-Xin ZhangJue LiuRong-Hai Yu
关键词:MICROSTRUCTURE
Structural analysis and magnetic properties of chemically synthesized composition-controlled Fe1-xCox particles
The composition-controlled micron-sized Fe1-xCox(0.2<x<0.75)particles with high purity have been prepare...
Xiaopan LiBai YangXueying YangYing CaoRonghai Yu
关键词:PARTICLESCOMPACTIBILITYMAGNETIZATION
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