＜正＞1,2-Migration is one of the fundamental reactions in transition metal-catalyzed reaction of a-diazo carbony...
XU, Feng WANG, Jian-Bo (Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871)
＜正＞ 1,2-Migration is one of the fundamental reactions in transition metal-catalyzed reaction of oc-diazo carbo...
Feng Xu, Weifeng Shi, and Jianbo WangKey Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871
As a continuation of the investigation on 1,2-migration of metal carbene and free carbene, two X-ray structures of β-substituted α-diazocarbonyl compounds were obtained. The relationship between the structure and 1,2-migratory aptitude was discussed and an exploratory photochemical study of the diazo compounds presented.
＜正＞ The Rh（Ⅱ）-carbene species generated from Rh（Ⅱ） catalyst and the diazo compound is highly reactive, which c...
Fengping Xiao, Weifeng Shi, Jian Zhang and Jianbo WangKey Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871
＜正＞ The catalytic asymmetric inductions in oxygen or sulfur ylides generated from carbenoids have attracted co...
Ming Ma, Lingling Peng, Changkun Li and Jianbo WangKey Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education. Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871
＜正＞ C-H bond insertion is an unique reaction of Rh（Ⅱ） carbene. In particular, the intramolecular C-H. insertio...
Bo Zhang, Weifeng Shi, Jian Zhang, Shiwei Zhang and Jianbo Wang.Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871
