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国家自然科学基金(11004092)

作品数:16 被引量:33H指数:4
相关作者:李成仁孙景昌王玉新郑亚茹崔硕更多>>
相关机构:辽宁师范大学大连理工大学更多>>
发文基金:国家自然科学基金辽宁省科技厅基金大连市科学技术基金更多>>
相关领域:理学机械工程一般工业技术化学工程更多>>

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16 条 记 录,以下是 1-10
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Li_(2)GeO_(3):Er^(3+),Yb^(3+)陶瓷基于泵浦功率的可调谐性研究
2022年
采用高温固相法制备了Li_(2)GeO_(3):x Er^(3+),y Yb^(3+)系列陶瓷材料,分析了铒、镱离子浓度对上转换光致发光强度的影响,得到优化的掺杂浓度分别为1.5和12 mol%.侧重讨论了980 nm半导体激光器激发下Li_(2)GeO_(3):1.5Er^(3+),12Yb^(3+)陶瓷发光颜色随泵浦功率的变化.结果表明,该样品具有从橙红色逐渐过渡到绿色的可调谐发射,调谐范围宽,且调谐方式便利.同时提出了定量描述可调谐发光材料调谐范围的表达式.
李成仁魏敬奇褚云婷赵峰赵倩韵
关键词:泵浦功率
衬底温度对ZnO:N薄膜结构和光学性能的影响被引量:5
2012年
利用超声喷雾热解方法,以不同的沉积温度(450~510℃)在石英衬底上制备出具备较高光学质量的氮掺氧化锌(ZnO:N)薄膜。通过X射线衍射(XRD)谱研究了薄膜的结构,用扫描电子显微镜(SEM)研究了薄膜的表面形貌,用紫外可见(UV)分光光度计、光致发光(PL)谱对薄膜的光学特性进行了测试分析。结果表明,所制备薄膜在可见波段具有较高透过率,并且沉积温度对ZnO:N薄膜的透过性能有很大影响。在衬底温度为500℃时得到的ZnO:N薄膜为六角纤锌矿结构,结晶质量最好、光透过率最高。PL谱的测试结果显示,在该条件制备的ZnO:N薄膜只在389.4nm处有一个较强的近带边紫外发光峰。
王玉新孙景昌郑亚茹王晓玉张焕戴世飞朱军
关键词:透过率光学性能
Intense up-conversion emissions of yb3+/Dy3+ co-doped A12O3 nanopowders prepared by non-aqueous sol-gel method*被引量:2
2012年
yb3+/Dy3+ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results show that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663 nm, corresponding to 4C9/2→ 6H13/2, 4C9/2→ 6Hll/2, 4115/2 → 6H13/2, and 4F9/2 →6Hll/2 transitions of Dy3+, respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion emissions. The energy transition between Yb3+ and Dy3+ is discussed.
李成仁李淑凤董斌孙景昌卜晓峰范旭楠
Photoluminescence of green nanophosphors Sr_(2)MgSi_(2)O_(7)doped with Tb^(3+)under 374-nm excitation
2021年
A series of Sr_(2)MgSi_(2)O_(7):Tb^(3+)nanophosphors is prepared using a high-temperature solid-state reaction.The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected by Tb^(3+)ions.However,the images of the scanning electron microscope illustrate that the average size of nanoparticles becomes larger with the increase of Tb^(3+)concentration.Unlike earlier investigations on down-conversion emission of Tb^(3+)ion excited by deep ultraviolet light,in this work,the photoluminescence characteristics of Sr_(2)MgSi_(2)O_(7)nanophosphors doped with different Tb^(3+)concentrations are analyzed under 374-nm excitations.The intense green emission at 545 nm is observed at an optimal doping concentration of 1.6 mol%.The main reason for the concentration quenching is due to the electric dipole-electric dipole interaction among Tb^(3+)ions.
Bo-Shi MuYi ZhangQing-Feng BianCheng-Ren LiZhi-Chao LiYun-Ting ChuFeng ZhaoJing-Chang Sun
The Inorganic-organic Hybrid Junction with n-ZnO Nanorods/p-polyfluorene Structure Grown with Low-temperature Aqueous Chemical Growth Method
2012年
The inorganic-organic hybrid junction was synthesized on ITO glass substrate, which was consisted of an n-type ZnO nanorods (NRs) grown by low-temperature aqueous chemical growth method and a p-type polyfluorene (PF) organic film fabricated by spin-coating. The experimental results indicate that densely and uniformly distributed ZnO nanorods are successfully grown on the PF layer. The thickness of the PF layer plays a dominant role for the current-voltage (I-V) characteristic of the ZnO NRs/PF inorganic-organic hybrid junction device, and a p-n junction with obviously rectifying behavior is achieved with optimal PF layer thickness. The photoluminescence (PL) spectrum covering the broad visible range was obtained from the n-ZnO nanorods/p-polyfluorene (PF) structure, which was originated from the combination of the PF-related blue emission and the ZnO-related deep level emission.
吴伟边继明SUN YinglanCHENG ChuanhuiSUN JingchangLIANG HongweiLUO YingminDU Guotong
关键词:POLYFLUORENEPHOTOLUMINESCENCE
超声喷雾热解法制备AZO薄膜及其光致发光性能研究被引量:10
2015年
利用超声喷雾热解法以乙酸锌、硝酸铝为Zn、Al源配制前驱体溶液,按不同的Zn、Al原子比(1∶0.02,1∶0.03,1∶0.04,1∶0.05和1∶0.06)在单晶硅(100)衬底上制备出具有较好光致发光性能的ZnO:Al(AZO)薄膜.采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和光致发光谱(PL)表征了样品的晶体结构、表面形貌和光致发光性能.结果表明:所制备样品属于纤锌矿ZnO结构,且择(002)取向生长,薄膜表面比较平整,具有较好的光致发光性能.并且Al掺杂量对AZO薄膜的紫外发射性能有重要影响,随着Al掺杂量的增加,紫外发射峰先蓝移后红移.在Zn、Al原子比为1∶0.04时得到的AZO薄膜结晶质量最好,蓝移量最大,光致发光性能最佳.
王玉新阎坤丛彩馨宋勇孙景昌吴齐张兴元
关键词:AZO薄膜光致发光谱表面形貌
新型WLED用Li_(2y-7)Sr_(4-1.5x)Eu_(x)(MoO_(4))_(y)红光纳米荧光粉被引量:1
2021年
高温固相反应法制备了系列Li_(2y-7)Sr_(4-1.5x)Eu_(x)(MoO_(4))_(y)纳米荧光粉.XRD结果表明,铕、锂离子的掺入对样品晶体结构影响甚微,但SEM图像表明掺杂锂离子后,荧光粉颗粒平均尺寸变小.激发谱显示存在着396和466 nm两个强的激发峰.Sr_(4-1.5x)Eu_(x)(MoO_(4))_(4)荧光粉在两种激发条件下,均获得强的617 nm红光,CIE坐标分别为(0.663,0.320)和(0.672,0.327).研究了荧光粉光致发光强度随掺铕和锶浓度的变化,优化浓度比为1.8∶1.3.讨论了Li^(+)浓度对Sr_(4-1.5x)Eu_(x)(MoO_(4))_(4)荧光粉发光谱的影响,优化掺锂浓度为2 mol%.
李成仁张熠边庆丰赵峰褚云婷
衬底温度对ZnO:Al薄膜结构和光透过性能的影响被引量:10
2012年
利用超声喷雾热解方法以不同的沉积温度(450~530℃)在石英衬底上制备出具备较高光学质量的ZnO:Al(AZO)薄膜.通过X射线衍射谱(XRD)研究了薄膜的结构,用扫描电子显微镜(SEM)研究了薄膜的表面形貌,用紫外可见(UV)分光光度计对薄膜的光透过特性进行了测试分析.结果表明:所制备薄膜在可见波段具有较高透过率,并且沉积温度对AZO薄膜的结构和光透过性能有很大影响.在衬底温度为470℃时得到的AZO薄膜具有(002)择优取向,结晶质量最好、光透过率最高,在可见光区平均透过率达到85%以上.
王玉新孙景昌郑亚茹王晓雪梁鸣林茂魁崔硕
关键词:AZO薄膜透过率
衬底温度对ZnMgO薄膜结构和光致发光性能的影响被引量:1
2013年
利用超声喷雾热解方法以不同的沉积温度(450~550℃)在石英衬底上制备出一系列ZnMgO薄膜。采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和光致发光谱(PL)表征了样品的晶体结构、表面形貌和光学性能。结果表明衬底温度对薄膜结构性能和光学特性影响显著。所有薄膜都呈六角纤锌矿多晶结构,其中在530℃条件下制备的样品C轴择优最明显,晶粒尺寸均匀,表面形貌平整,结晶质量最好。薄膜的光致发光谱显示随着温度的升高深能级跃迁范围逐渐减小,近紫外带边发光峰逐步出现。衬底温度为530℃时在374.5nm处出现了明显的近紫外发光峰,且几乎没有明显的深能级跃迁出现。
董李娜王玉新孙景昌郑亚茹张焕梁鸣林茂魁崔硕
关键词:ZNMGO薄膜衬底温度光致发光谱
Synchronization investigation of the network group constituted by the nearest neighbor networks under inner and outer synchronous couplings
2016年
A new synchronization technique of inner and outer couplings is proposed in this work to investigate the synchro- nization of network group. Some Haken-Lorenz lasers with chaos behaviors are taken as the nodes to construct a few nearest neighbor complex networks and those sub-networks are also connected to form a network group. The effective node controllers are designed based on Lyapunov function and the complete synchronization among the sub-networks is realized perfectly under inner and outer couplings. The work is of potential applications in the cooperation output of lasers and the communication network.
李亭亭李成仁王晨何芳君周光冶孙景昌韩非
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