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国家自然科学基金(61271038)

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The low-temperature sintering and microwave dielectric properties of (Zn_(0.7)Mg_(0.3))TiO_3 ceramics with H_3BO_3被引量:1
2013年
The effects of the addition of H3BO3 on the microstructure, phase formation, and microwave dielectric properties of (Zn0.TMg0.3)TiO3 ceramics sintered at temperatures ranging from 890 ℃ to 950 ℃ are investigated. H3BO3 as a sintering agent can effectively lower the sintering temperature of ZMT ceramics below 950 ℃due to the liquid-phase effect. The microwave dielectric properties are found to strongly correlate with the amount of H3BO3. With the increase in H3BO3 content, the dielectric constant (er) monotonically increases, but the quality factor (Q x f) reaches a maximum at 1 wt% H3BO3, and the apparent density of ZMT ceramics with H3BO3〉 1 wt% gradually decreases. At 950 ℃, the ZMT ceramics with 1% H3BO3 exhibit excellent microwave dielectric properties: er = 19.8, and Q x f -- 43800 GHz (8.94 GHz).
沈国策苏桦张怀武荆玉兰唐晓莉
关键词:LTCC
CaWO_4-Li_2WO_4陶瓷低温烧结特性及微波性能研究
2014年
采用固相反应法制备了(1-x)CaWO4-xLi2WO4(0≤x≤0.14)微波陶瓷,研究了Li2WO4作为第二相对CaWO4微波陶瓷的低温烧结特性和微波性能的影响。结果表明,Li2WO4相的存在能明显降低CaWO4的烧结温度,并且随着x的增加,(1-x)CaWO4-xLi2WO4(0≤x≤0.14)陶瓷体系的最佳烧结温度降低。当x=0.1,在900℃下烧结2h,该陶瓷材料的介电常数εr=9.002,品质因数与频率之积Q×f=11.76×104 GHz,谐振频率温度系数τf=-55×10-6/℃。在此基础上采用w(CaTiO3)=5.0%调节其谐振频率温度系数到0,调节后的微波介电性能为εr=10.312,Q×f=5.36×104 GHz。
章著苏桦唐晓莉张磊江超荆玉兰
关键词:微波介电性能低损耗
Effects of BaCu(B_2O_5 ) addition on sintering temperature and microwave dielectric properties of Ba_5Nb_4O_(15)–BaWO_4 ceramics被引量:1
2014年
The effects of BaCu(B2Os) (BCB) addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu(B2Os) ceramic could effectively lower the sintering temperature of BasNb4015-BaWO4 ceramic from 1100 ℃ to 950 ℃ due to the liquid-phase effect. Meanwhile, BaCu(B2Os) addition effectively improves the densification of BasNb4015-BaWO4 ceramic and significantly influences the microwave dielectric properties. X-ray diffraction analysis reveals that BasNb4015 and BaWO4 coexist with no crystal phase of BaCu(B2Os) in the sintered ceramics. The BasNb4015-BaWO4 ceramics with 1.0 wt% BaCu(B2Os) sintered at 950 ℃ for 2 h presents good microwave dielectric properties of er = 19.0, high Q× f of 33802 GHz and low vf of 2.5 ppm/℃.
贾瑞龙苏桦唐晓莉荆玉兰
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