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国家自然科学基金(40775080)

作品数:2 被引量:4H指数:1
相关作者:叶兴南陈建民乐英红更多>>
相关机构:复旦大学更多>>
发文基金:国家自然科学基金国家教育部博士点基金更多>>
相关领域:环境科学与工程化学工程更多>>

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A Multifunctional HTDMA System with a Robust Temperature Control被引量:3
2009年
The hygroscopicity of atmospheric aerosols significantly influences their size distribution, cloud condensation nuclei ability, atmospheric residence time, and climate forcing. In order to investigate the hygroscopic behavior of aerosol particles and serious haze in China, a Hygroscopic Tandem Differential Mobility Analyzers (HTDMA) system was designed and constructed at Fudan University. It can function as a scanning mobility particle sizing system to measure particle size distribution in the range of 20-1000 nm in diameter, as well as a hygroscopicity analyzer for aerosol particles with diameters between 20-400 nm in the range of 20%-90% RH (relative humidity). It can also measure the effect of uptake of inorganic acids or semiVOCs on the hygroscopic behavior of aerosols, such as typical inorganic salts in atmospheric dust or their mixtures. The performance tests show that the system measured particle size of the standard polystyrene latex spheres (PSLs) is 197 nm, which is in excellent agreement with the certified diameter D=199±6 nm, as well as a standard deviation of the repeated runs SD=8.9×10^-4. In addition, the measured hygroscopic growth factors of the model compounds, (NH4)2SO4 and NaNO3, agree with the Kohler theoretical curves. The results indicate that the HTDMA system is an excellent and powerful tool for studying the hygroscopic behavior of submicron aerosols and meets the demand required for laboratory research and fieldwork on atmospheric aerosols in China.
叶兴南陈天翼胡大伟杨新陈建民张人一Alexei F.KHAKUZIV王琳
关键词:HTDMAEVALUATION
Nano-size Distribution of Aerosol from Agricultural Residues Burning Matched to Optical Properties:A Laboratory Study
<正>Laboratory measurements were conducted with a chamber to determine the size distribution and scattering coe...
Dawei Hu~1 Xingnan Ye~1 Hefeng Zhang~1 Tiantao Cheng~(1,2*) Jianmin Chen~(1*) Zhiwei Han~2 Renjian Zhang~2 (1.Center of Atmospheric Chemistry Study,Department of Environmental Science & Engineering, Fudan University,Shanghai 200433,China
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α-龙涎醇的绿色合成被引量:1
2009年
考察了NaY沸石催化香叶基丙酮(GA)环合制备α-龙涎醇的活性。结果表明,溶剂的促进作用顺序为:CH2Cl2>CHCl3>Cl(CH2)2Cl>C6H12>CH3NO2~C6H6。当m(GA)∶m(NaY)=1∶2,NaY为8g,CH2Cl2为80mL,40℃反应2h时,GA转化率为100%,产物对α-龙涎醇的选择性为80%。再生NaY沸石的催化转化效率同比下降7%~8%。提出了NaY酸催化GA的环化反应机理。
叶兴南陈建民乐英红
关键词:NAY沸石催化
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