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山西省自然科学基金(2011011020-2)

作品数:11 被引量:46H指数:4
相关作者:侯利锋卫英慧郭春丽杜华云肖涛更多>>
相关机构:太原理工大学中国科学院宁波材料技术与工程研究所吕梁学院更多>>
发文基金:山西省自然科学基金国家自然科学基金中国博士后科学基金更多>>
相关领域:金属学及工艺一般工业技术更多>>

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11 条 记 录,以下是 1-10
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磷酸钠在NaCl溶液中对AZ31镁合金的缓蚀作用被引量:11
2015年
采用电化学阻抗法、动电位极化曲线法、全浸泡失重法和扫描电镜,研究了在3.5%(质量分数)Na Cl溶液中磷酸钠(Na3PO4)对AZ31镁合金腐蚀的抑制作用。结果表明:Na3PO4对3.5%Na Cl溶液中的AZ31镁合金具有缓蚀作用,其缓蚀率随着Na3PO4含量增大逐渐提高,当Na3PO4质量浓度为1.0 g/L时,缓蚀率达到81.5%。结合扫描电镜分析表明,Na3PO4在镁合金表面形成含有Mg(OH)2和Mg3(PO4)2的保护层,这层致密的膜减少了基体与Cl-接触,抑制了镁合金的阳极反应。
周娜侯利锋卫英慧郭春丽杜华云
关键词:AZ31镁合金电化学阻抗谱极化曲线
镁合金在多因素耦合作用下的腐蚀行为被引量:1
2014年
选择铸态和挤压态AZ61镁合金,采用SEM、XRD和电化学测试等分析手段,研究在120℃和1.8 MPa的NaCl气氛中镁合金的腐蚀形貌和腐蚀机理。结果表明,在NaCl气氛、温度、压力和合金组织状态等多因素耦合作用下,由于β相重新分布以及晶粒尺寸变小,使得挤压态AZ61镁合金的腐蚀速率大于铸态的腐蚀速率,但腐蚀产物均以Mg(OH)2为主。较高的温度与NaCl气氛共同作用是加快镁合金腐蚀的主要原因。
侯利锋田赟李永刚卫英慧
关键词:镁合金
基于Fluent的GTAW数值模拟被引量:3
2016年
基于GTAW特点,建立了包含阴极、电弧和阳极的完整耦合的瞬态统一模型。利用Fluent软件模拟,并对其UDF进行二次开发,研究了0Cr18Ni9Ti在GTAW下的熔池和电弧的形态。计算了不同时刻电弧温度场和熔池形状,其结果表明随着焊接时间的延长,电弧形状变化较小,熔池形状变化较大,熔池呈现出勺形特征。熔池内流体在电磁力、表面张力的主要作用下形成3个涡流。在这3个涡流综合作用下,促使了熔池勺形形状的形成。计算结果在理解分析GTAW物理过程以及熔池形状机理方面上,具有一定的理论参考价值。
刘凤磊杜华云安艳丽卫英慧樊丁
关键词:熔池电弧
木质素磺酸钠对3.5%NaCl溶液中AZ31镁合金的缓蚀作用被引量:5
2016年
采用失重法,极化曲线,电化学阻抗谱和扫描电子显微镜研究木质素磺酸钠(SLS)在质量分数为3.5%NaCl溶液中对AZ31镁合金的缓蚀作用。结果表明:在298 K时SLS可有效抑制AZ31在Na Cl介质中的腐蚀。当SLS为4.0 g·L^(-1)时,缓蚀率可达到最大。提高浓度后,其缓蚀率会下降。SLS是阴极型缓蚀剂,并且SLS在AZ31表面的吸附符合Langmuir吸附模型。由吸附自由能?G^0及Arrhenius活化能E_a可知,SLS在AZ31镁合金表面是化学吸附。
肖涛党宁侯利锋卫英慧郭春丽杜华云
关键词:镁合金木质素磺酸钠缓蚀剂NACL溶液
Microstructure and Mechanical Properties of TWIP Steel Joints被引量:7
2014年
As a new type of high manganese steel, the twinning induced plasticity (TWIP) steels have attracted a growing interest in the automotive industry due to their good performance. Thin plates of TWIP steel were welded by laser beam welding (LBW) and gas tungsten arc welding (GTAW). The microstructure result shows that GTAW joint has obvious heat-affected zone (HAZ), while the HAZ of LBW joint is almost invisible. The X-ray diffraction result shows that the phase compositions of both joints are austenitic and no phase transition occurs. Energy disper- sive spectrometry result shows that there is violent evaporation of Mn element in LBW joint, while the proportion of Mn element in GTAW joint is almost unchanged. Tensile tests and micro-hardness measurements were performed to take into account the mechanical properties of joints manufactured by the two different processes. The micro-hard- ness profiles of both joints present a typical saddle distribution, and the hardness of GTAW seam is lower than that of LBW seam. The failure positions of LBW joints are all located in base metal while the GTAW joints are all at the weld toe due to the softening of HAZ. By means of scanning electron microscopy, a typical ductile fracture is observed in LBW joint, while a brittle fracture with quasi-cleavage fracture characteristic is observed in GTAW joint.
Li-li MAYing-hui WEILi-feng HOUBin YAN
关键词:GTAW
新喀里多尼亚弧菌胞外聚合物对硫酸中Q235碳钢的缓蚀作用被引量:4
2016年
采用电化学阻抗测试、极化曲线测试和扫描电镜观察等方法研究了在25℃条件下新喀里多尼亚弧菌胞外聚合物(EPS)对Q235碳钢在0.5 mol/L H2SO4溶液中的缓蚀作用。结果表明:该弧菌EPS能够在碳钢表面形成一层较为致密的Fe-EPS保护层,可有效抑制H_2SO_4溶液对Q235钢的腐蚀。随着EPS浓度的增加,缓蚀效率增大;当EPS浓度为1.0 g/L时,缓蚀效率最高。EPS在Q235钢表面的吸附为自主的化学吸附且符合Langmuir吸附模型。通过Fourier红外吸收光谱确定了该EPS的成分。
肖涛Masoumeh Moradi宋振纶杨丽景闫涛侯利锋
关键词:弧菌胞外聚合物缓蚀化学吸附
新喀里多尼亚弧菌对Cu在人工海水中腐蚀行为的影响被引量:4
2016年
分离出了一种具有高度缓蚀作用的新喀里多尼亚弧菌,通过电化学测量方法和表面分析技术研究了该细菌对Cu在人工海水中腐蚀行为的影响。结果表明,新喀里多尼亚弧菌使Cu的开路电位明显负移;在有菌介质中,Cu表面的阻抗值显著增大;同时腐蚀电流密度明显降低,说明该细菌可以抑制Cu在人工海水中的腐蚀。CLSM结果显示,Cu表面吸附有大量的细菌,而SEM观察到Cu表面生物膜并不多,说明这种抑制作用是由吸附在Cu表面的细菌引起的,而与Cu表面的生物膜关系不大。
闫涛宋振纶Masoumeh Moradi杨丽景肖涛侯利锋
关键词:CU缓蚀作用
Evaluation on Fatigue Performance and Fracture Mechanism of Laser Welded TWIP Steel Joint Based on Evolution of Microstructure and Micromechanical Properties被引量:4
2016年
The fatigue performance and fracture mechanism of laser welded twinning induced plasticity(TWIP)steel joint were investigated experimentally based on the evolution of microstructure and micromechanical properties.The optical microscopy was used to analyze the evolution of microstructure.The variation of composition and phase structure of fusion zone were detected by energy dispersive X-ray and X-ray diffraction spectrometers.The micromechanical behaviors of the various zones were characterized using nanoindentation.The static tensile test and high cycle fatigue test were performed to evaluate the mechanical properties of welded joint and base metal.The microstructures,tensile properties and fatigue strength of base metal as well as welded metal were analyzed.The fatigue fracture surfaces of base metal and welded joint were observed by means of scanning electron microscopy,in order to identify fatigue crack initiation sites and propagation mechanisms.Moreover,the fatigue fracture characteristics and mechanisms for the laser welded TWIP steel joints were analyzed.
Li-li MAYing-hui WEILi-feng HOUChun-li GUO
Effect of erbium on microstructures and properties of Mg-Al intermetallic被引量:2
2014年
The effect of the rare earth element Er on the microstructures and properties of Mg-Al intermetallic were studied in this experiment. Metallographic and X-ray diffraction(XRD) results showed that the microstructures of Mg-Al-Er alloys varied with Er content. The Mg-44Al-0.5Er and Mg-43.8Al-1.0Er alloys were both composed of Mg17Al12 matrix and Al3 Er phase, whereas Mg-43Al-3.0Er and Mg-42Al-5.0Er were composed of Mg17Al12 matrix, Al3 Er phase, and Mg-Mg17Al12 eutectic. The Mg-42Al-5.0Er alloy showed the highest microhardness, and the values remained nearly stable as Er content increased from 1.0 wt.% to 5.0 wt.%. The dispersed second phase Al3 Er caused the grain refinement of the Mg-Al-Er alloy, which was the main reason for the improvement in microhardness. The corrosion resistance of the Er-containing alloys initially increased and then decreased with increasing Er content. All the Er-containing alloys had the ability to suppress hydrogen evolution, which was the main reason for the higher corrosion resistance of the modified alloys than that of the Mg-44.3Al alloy. Considering the higher hardness and dispersity of the Al3 Er phase, Mg-43.8Al-1.0Er exhibited higher wear resistance than the as-cast Mg-44.3Al alloy.
李永刚卫英慧侯利锋郭春丽韩鹏举
关键词:PRECIPITATES
纯铜表面机械研磨辅助制备镍合金层被引量:5
2014年
以纯铜为研究对象,通过添加镍粉进行表面机械研磨(SMAT)处理。用光学显微镜(OM)、X射线衍射分析仪(XRD)和扫描电镜(SEM)对SMAT处理后样品的组织及成分变化进行分析。采用X射线能量色散谱分析方法(EDS)分析Ni元素在合金层中的分布与含量。结果表明,纯铜表面出现了明显的分层现象,同时铜镍发生互扩散有铜镍合金形成。处理120 min后形成厚度为35μm铜镍合金层,而240 min厚度则达到55μm,并且合金层与基体变形层结合紧密。由于弹丸的冲击产生应力应变和大量储存能,使得原子的跳动频率增加同时降低了扩散激活能,实现铜镍在较低温度下快速互扩散。
侯利锋王磊卫英慧郭春丽李宝东
关键词:纯铜表面机械研磨合金层
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