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国家自然科学基金(51071136)

作品数:7 被引量:40H指数:4
相关作者:王明家陈雷张勇王艳马千更多>>
相关机构:燕山大学唐山钢铁集团有限责任公司清华大学更多>>
发文基金:国家自然科学基金国家高技术研究发展计划更多>>
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Effect of rare earth elements on the thermal cracking resistance of high speed steel rolls被引量:10
2011年
The effect of rare earth elements on the thermal cracking resistance of high speed steel (HSS) rolls was investigated. Laser rapid heating was used for thermal fatigue experiments. Thermal cracks and microstructure were observed using metalloscopy and scanning electron microscopy. The results showed that thermal cracks initiated from the interface between the matrix and eutectic carbides (including M6C and M7C3 type carbides),and propagated along the interface between the two phases. MC type carbides enriched with vanadium could prevent the propagation of thermal cracks. The presence of rare earth elements decreased the quantity of big eutectic carbides,and proportionally increased spherical and rod-shaped MC type carbide content. HSS0 (0.00% RE) had approximately three times the thermal cracking density of HSS3 (0.12 wt.% RE). Rare earth elements were shown to significantly improve the microstructure and thermal cracking resistance of HSS rolls.
王明家李艳美王子兮包耳
Influence of rare earth elements on solidification behavior of a high speed steel for roll using differential scanning calorimetry被引量:2
2011年
The influence of rare earths(RE) on solidification behavior of a high speed steel for roll was investigated by using differential scanning calorimetry(DSC) in combination of microstructure analysis.It was found that the sequence of solidification was L→γ,L→γ+MC,L→γ+M2C,L→γ+M6C,respectively.The start temperature and the latent heat liberated by unit mass of L→γ and L→γ+MC increased with increase of RE addition,indicating that RE could trigger the crystallization of the primary γ and the MC carbide more effectively.The promoting effect of RE on the heterogeneous nucleation was believed to be an important cause of this effect.Grain refinement,discontinuous network of eutectic carbides and disperse and finer MC were observed in the samples with RE addition,moreover,RES could act as the heterogeneous nucleus of the MC.RE addition was favorable for stable M6C at the expense of the metastable M2C.
王明家陈雷王子兮包耳
关键词:SOLIDIFICATIONDSC
含稀土轧辊用高速钢淬回火过程微观组织转变被引量:3
2012年
利用金相(OM)、扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)及能损谱(EELS)等手段,研究了含稀土轧辊用高速钢在1100℃淬火和550℃两次回火热处理过程的微观组织变化特征,重点探讨了碳化物行为。结果表明,淬火加热过程中热稳定性较高的MC和M6C型一次共晶碳化物难以溶解,亚稳态的M2C型一次共晶碳化物则发生分解反应得到MC和M6C两种碳化物,分解形成的M6C较MC量多且尺寸较大,小颗粒MC包含在M6C之中;淬火基体组织由马氏体和残留奥氏体组成,淬火马氏体既有板条马氏体也有孪晶型马氏体。经两次回火后,残留奥氏体得以有效消除,大量细小富V的MC型二次碳化物弥散析出产生二次硬化现象。
王明家陈雷王子兮李喆
关键词:高速钢轧辊碳化物回火
固溶态316LN不锈钢的氧化行为被引量:5
2012年
研究了固溶态316LN不锈钢在900~1200℃空气中的氧化行为。结果表明,316LN不锈钢在900~1200℃范围内氧化增重与氧化时间的关系遵从抛物线规律,氧化速率常数kT随温度的升高而增大;316LN不锈钢的高温氧化具有选择性,氧化首先发生于富Cr的晶界处;900℃时氧化轻微,氧化膜主要为Cr2O3,1000℃时氧化膜组成为Cr2O3和尖晶石结构的MnCr2O4,1200℃时除Cr2O3和MnCr2O4外,还存在少量的FeCr2O4。316LN不锈钢的氧化激活能为278.765 kJ/mol,氧化速率常数为8.05×105exp{-278265/(RT)}。
王明家信瑞山龙珊珊褚春光
关键词:固溶态氧化动力学
Investigation of Impact Toughness of Electromagnetic Centrifugal Cast High Speed Steel
2012年
The effect of external magnetic field on the solidification structure and impact toughness of high-speed steel(HSS)produced by electromagnetic centrifugal casting(EMCC)have been investigated.It was found that the solidification structure could be improved effectively by electromagnetic stirring,which was characterized by elimination of the inclined columnar dendrites and refinement of the grain size.The results may be related to the changes of the fluid layers of liquid-solid phase interface.Moreover,the impact toughness of the test steel increased with the exciting current increasing from 12 to 18 A,but decreased when the current was above 18 A.SEM analysis showed that impact fracture surface was dimple fracture due to effect of the refined equiaxed grains when the current was 18 A,which was considered an important reason for the improvement of impact toughness.
WANG Ming-jiaGU TaoWANG Zi-xi
热老化对核级316LN锻造控氮奥氏体不锈钢微观组织及性能的影响被引量:13
2013年
研究了热老化对核级316LN锻造奥氏体不锈钢的位错组态、电阻率及显微硬度的影响规律。结果表明,随着热老化的进行,奥氏体基体中位错密度总体下降,而始于晶界向晶内延伸的扩展位错数量增多且宽度变窄,其中,固溶态的扩展位错宽度约为1.0 m,热老化5 000 h后约为0.2 m。分析认为,碳原子在晶界及其附近微区的偏聚是引起位错亚结构变化的主要原因;电阻率随热老化时间的延长、检测温度的升高而增大,且热老化5000h后电阻率随温度的增长速率高于固溶态;晶内和晶界处的显微硬度值随热老化的进行均有所升高,二者之间显微硬度的差值逐渐增加。
王明家马千李景丽张勇王艳陈雷
关键词:热老化位错组态显微硬度
Effect of rare earth addition on continuous heating transformation of a high speed steel for rolls被引量:7
2012年
The effect of rare earth(RE) on continuous heating transformation of a high speed steel for rolls was investigated by using differ-ential scanning calorimetry(DSC) with combination of microstructure analysis.Determination of the Ac1 and Ac3,the starting temperature of carbide dissolution and melting upon heating,the enthalpy change for the α→γ transformation and overall carbide dissolution were also es-tablished.It was found that RE could reduce the volume fraction of large eutectic carbides and the chrysanthemum-like eutectic colonies but could not change the phase composition.RE made a little change to Ac1,but the variation in Ac3 and enthalpy for the α→γ followed an in-creasing pattern as the RE addition increased.The start temperatures of carbides dissolution increased with increase of RE addition,which may be associated with the influences of RE on the morphology of carbides,but the overall enthalpy change of carbides dissolution decreases as the RE addition increased.Moreover,the start temperature of melting also increased with increasing RE addition.
WANG MingjiaCHEN LeiWANG ZixiBAO Er
关键词:DSC
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