The high-temperature tensile fracture behavior of the Ni, Cr, Al-TaC eutectic superal-loy directionally solidified under high temperature gradient is investigated. The high-temperature tensile fracture of this in situ composite has ductile character with lots of ductile nests whose diameters decrease with the increasing solidification rates. The maximum σb and δ are respectively 668.5MPa and 19.6%. There is α TaC whisker in the center of each nest, and the deformation of γ' and TaC is uneven. The high-temperature tensile behavior cannot be explained by the rule of mixtures but is decided by the formation of the plastic deformation band. The crack extension model is given.
The Si-TaSi2 eutectic in situ composite for field emission is prepared by electron beam floating zone melting (EBFZM) technique on the basis of Czochralski (CZ) crystal growth technique. The directional solidification microstructure and the field emission properties of the Si-TaSi2 eutectic in situ composite prepared by two kinds of crystal growth techniques have been systematically tested and compared. Researches demonstrated that the solidification microstructure of EBFZM can be fined obviously be-cause of the relatively high solidification rate and very high temperature gradient, i.e. both the diameter and inter-rod spacing of the TaSi2 fibers prepared by EBFZM technique were decreased, and the density and the volume fraction of the TaSi2 fibers prepared by EBFZM technique were increased in comparison with that of the TaSi2 fibers prepared by CZ method. Therefore the field emission property of the Si-TaSi2 eutectic in situ composite prepared by EBFZM can be improved greatly, which exhibits better field emission uniformity and straighter F-N curve.
CUI ChunJuanZHANG JunHAN MinCHEN JunXU NingShengLIU LinFU HengZhi
Laser remelting and rapid solidification were performed in preparing the high-performance Al2O3/Y3Al5O12(YAG) eutectic in situ composite. The microstructure characteristic and solidification behavior were studied using scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), X-ray diffractometry(XRD) and simultaneous thermal analysis(STA). The hardness and fracture toughness were obtained using an indentation technique. The results show that the laser remelted Al2O3/YAG composite has a homogeneous eutectic microstructure without microcrack and pore. The component phases of Al2O3 and YAG are three-dimensionally and continuously reticular connected, and finely coupled without grain boundaries, colonies and amorphous phases between interfaces. The eutectic interspacing is greatly refined with increasing the scanning rate and average is only 1 μm. The synthetically thermal analysis indicates that the eutectic temperature of Al2O3-YAG is 1 824 ℃, well matching the phase diagram of Al2O3-Y2O3 system. The maximum hardness reaches 19.5 GPa and the room fracture toughness is 3.6 MPa·m1/2.
