A series of CexZr1-xO2(0 B x B 1)with different molar ratios of Ce/Zr were syhthesized via coprecipitation method,and Fe2O3-WO3/CexZr1-xO2monolithic catalysts were prepared for selective catalytic reduction of nitrogen oxides by ammonia(NH3-SCR).The structural properties and redox behavior of the catalysts were comprehensively characterized by N2physisorption,X-ray diffraction(XRD),X-ray photoelectron spectra(XPS),H2-temperature programmed reduction(H2-TPR)and activity measurement for NH3-SCR.The results showed that the NH3-SCR activities of the catalysts were gradually enhanced by increasing the molar ratios of Ce/Zr,especially the lowtemperature catalytic activity and the reaction temperature window.Fe2O3-WO3/Ce0.68Zr0.32O2monolithic catalyst presented the best NH3-SCR activity among the investigated catalysts,more than 90%NOxcould be removed in the temperature range of 247–454°C on the catalyst under the gas hourly space velocities of 30,000 h-1.And it always held more than 99%N2selectivity and less than 20 ppm(1 ppm=10-6L/L)N2O generation concentration between 200 and500°C,the catalyst also displayed its strong resistance of H2O and SO2.Good textural and structural properties,more surface Fe,Ce and active oxygen were together contributed to the excellent NH3-SCR performance of Fe2O3-WO3/Ce0.68Zr0.32O2catalyst.
文章针对柴油机微粒捕集器(diesel particulate filter,DPF)的再生展开相应的研究。利用降怠速再生试验(drop-to-idle,DTI)确定载体碳载量限值,利用台架试验研究了缸内次后喷(late post injection,LPI)基于不同再生温度与再生时间对再生效率和排放性能的影响。结果表明:3.0g/L的碳载量水平满足DTI的试验要求且适宜再生试验研究,可以避免在再生突然中断后DPF内部温度迅速升高,避免载体烧融;再生时间维持在2min左右,再生时DPF出口温度维持在500℃左右时,DPF再生效率高达98%,装载碳烟几乎完全燃烧,且DPF内部温度和出口温度可控,保证了DPF安全可靠再生,同时增加了DPF使用寿命;对整个再生过程中尾气成分进行分析和计算,发现柴油机尾气中HC为主要二次污染物,且排放相对较大。
Fresh Pd/CeO_2/Al_2O_3 close coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these pretreated catalysts were aged at 1000 °C for 3 h to study their anti-aging properties. The catalytic activities of the catalysts were investigated detailedly, and the results showed that the catalyst pretreated at 800 °C before aging treatment possessed the best anti-aging performance for C_3H_8 oxidation. XRD and XPS results indicated that well-crystallized CeO_2 particles were formed during calcinations at 800 °C, which made CeO_2 an effective promoter. HRTEM revealed that Pd particles found on the edge of CeO_2 over the aged catalyst pretreated at 800 °C were relatively smaller than those over the catalysts without pretreatment. H_2-TPR and XPS results also implied that the interaction between well-crystallized CeO_2 and Pd suppressed the deactivation of PdO sites and further enhanced the catalytic performance.
