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国家自然科学基金(40972003)

作品数:11 被引量:57H指数:6
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Lower Triassic and Induan-Olenekian Boundary in Chaohu,Anhui Province,South China被引量:10
2011年
Since the West Pingdingshan Section in Chaohu was proposed as the candidate of the Global Stratotype Section and Point of the Induan-Olenekian boundary in 2003, the Lower Triassic of Chaohu has been extensively studied. Based on the studies on the Lower Triassic of Chaohu, (1) a continuous conodont zonation is established, which has become an important reference for Lower Triassic stratigraphic correlation over the world; (2) the First Appearance Datum of conodont Neospathodus waageni was suggested and has been basically accepted as the primary marker to define the InduanOienekian boundary; (3) a characteristic Lower Triassic excursion of carbon isotopes was brought to light and has been proven to be not only an excellent index for the stratigraphic correlation but also a unique indication for the perturbation of ecological environments in the aftermath of the end-Permian mass extinction; (4) a magnetostratigraphic sequence is constituted with a certain biostratigraphic control in the low-latitude region and it presents an important correlation to the Boreal sequence; (5) a cyclostratigraphic study provides an alternative method to constrain the age of the chronostratigraphic units; and (6) a scheme of the Olenekian subdivision is recently suggested to define the boundary between the Smithian and Spathian Substages. In addition, Chaohu is also the type locality of the Chaohuan Stage, the upper stage of the Lower Triassic in the China Chronostratigraphic System.Thus, the Lower Triassic of Chaohu is not only a classic sequence in South China, but also a key reference sequence to the investigation of the corresponding stratigraphy and geological events over the world. The recent achievements are viewed here for an overall understanding of the sequence. Then the current situation of the Induan-Olenekian and Smithian-Spathian boundaries is discussed to provide a reference for later works.
TONG JinnanZHAO Laishi
关键词:CHAOHU
Lower Triassic Smithian-Spathian Boundary at West Pingdingshan Section in Chaohu,Anhui Province被引量:8
2011年
The West Pingdingshan Section in Chaohu, Anhui Province, has been extensively studied in recent years and become one of the classic Lower Triassic sequences well-clarified in multiple stratigraphies. Also it is an important section that defines the Smithian-Spathian (S-S) boundary within the Olenekian Stage. The S-S boundary strata at the section are restudied in high-resolution conodont biostratigraphy and carbon isotopes. The refined S-S boundary defined by the FAD of conodont Neospathodus pingdingshanensis is at 30 cm above the base of Bed 52, corresponding to a rapid diversification of conodonts. A sharp positive shift of δ13Ccarb curve co-occurs at the S-S boundary and it can be used as a key reference to define the boundary. The defined S-S boundary position and carbon isotopes curve can be well correlated globally.
LIANG DanTONG JinNanZHAO LaiShi
关键词:CONODONTCHAOHU
浙江长兴煤山全球界线层型剖面牙形石微量元素微区分析
古海相沉积岩中可靠的微量元素记录可以很好地揭示海洋物质的输入量和海水的化学成分特征,它们对于理解古海洋的长期演化以及与缺氧事件有关的生物大绝灭事件及其原因等具有非常重要的指示意义(Reynard et al.,1999;...
赵来时袁鹏陈建波周炼胡兆初
关键词:牙形石微量元素
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早三叠世下扬子古海洋地球化学环境的修复过程被引量:13
2013年
巢湖平顶山北坡剖面下三叠统岩石化学成分分析表明,SiO2、Al2O3、Fe2O3、FeO、MgO、Na2O、K2O、TiO2、P2O5及微量元素Ba、V、Be、Nb、Zn、Cu、Ni、Co、Pb主要富集在下三叠统格里斯巴赫(Griesbachian)、迪纳(Dienerian)及斯密斯(Smithian)亚阶中,形成了8次显著的正异常,异常的强度、规模由下向上呈下降趋势;微量元素Sr和常量元素CaO主要富集在下三叠统上部斯帕斯(Spathian)亚阶中,其含量由下向上呈逐渐增加趋势.前者含量与碳酸盐岩的碳同位素组成(δ13C)呈负相关关系,后者含量与碳酸盐岩的碳同位素组成(δ13C)呈正相关关系.海相碳酸盐岩碳同位素组成(δ13C)指示初始生产力大小,同时亦是海洋生态环境改善的指示标志;负相关表明环境恶化、生物萧条,正相关表明环境适宜、生物繁盛.据常量元素和微量元素分布异常特点在下三叠统地层中识别出8次地质事件,其规模及影响强度由早到晚逐渐变小及减弱;晚二叠世末期及早三叠世初期的火山喷发将各种有害元素大量输向海洋,导致海水中粘土矿物、微量元素含量异常增高,海洋生态环境恶化.随着时间推移,火山活动逐渐平息,海洋中各种有害组分逐渐排除,海水得到净化,生态环境渐渐恢复.
左景勋童金南赵来时常德峰赵荣军
关键词:化学成分古海洋早三叠世沉积物地球化学
The environmental index of the rare earth elements in conodonts:Evidence from the Ordovician conodonts of the Huanghuachang Section,Yichang area被引量:6
2012年
High-resolution microanalysis was performed on conodonts collected from the Huanghuachang section in the Yichang area using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). This region is regarded as a standard section for the division and correlation of the Ordovician system in southern China. The results show that the values of (La/Yb)N and (La/Sm)N decrease, while the values of δCe increase as seawater deepens and energy decreases. As the sedimentary environment changes from shallow-water carbonate platform to platform margin to open continental shelf to shelf basin, rare earth element distribution curves gradually transform from a right inclined pattern to a flat pattern to a left inclined pattern and a hat-shaped pattern. The present work proves that the values and distributive patterns of rare earth elements in conodonts correspond with the sedimentary environment, and therefore provide reliable evidence for the application of rare earth element concentrations of biogenic phosphates such as conodonts for palaeoenvironmental reconstructions.
CHEN XiaoHongZHOU LianWEI KaiWANG JinLI ZhiHong
关键词:牙形石环境指标LA-ICP-MS
酸碱条件下莫来石形成机理研究被引量:2
2011年
以正硅酸乙酯(C8H20O4Si),硝酸铝(Al(NO3)3.9H2O)为主要原料,氨水调节pH值,通过溶胶凝胶法制备出酸碱条件下纯相莫来石粉体。通过热分析得知粉体在升温过程中吸热、放热和晶相转换过程;通过XRD研究了凝胶在热处理过程中的结晶变化;通过红外吸收光谱测定了粉体中Si-O-Al键的存在和变化;通过环境扫描电子显微镜测定研究了莫来石粉末的表面特性。最终得出凝胶转变至莫来石的相变过程:酸碱条件下莫来石的生成过程都经历了由无定形铝和无定形硅转变为硅铝尖晶石再到莫来石的过程;在碱性条件下,莫来石开始转变温度低于酸性;同时生成的莫来石中,碱性条件比酸性条件粒度小。
张跃峰雷新荣陈安忠蒋涛
关键词:莫来石酸性碱性
Clay Rocks around Permian-Triassic Boundary at Daxiakou Section in Hubei Province,China
2009年
We studied the clay rocks around the Permian-Triassic boundary at the Daxiakou (大峡口) Section in Xingshan (兴山), Hubei (湖北) Province, China. All clay rocks are predominated by illitemontmorillonite (I/M) mixed-layer minerals, and high-temperature hexagonal bipyramid (HB) quartz and pyrite are contained in different abundances. Clay microspheres are even found in some beds. The results show that volcanic activity was very frequent in this area or in the neighboring areas during the Permian-Triassic transition though the intensity of eruption and the position of the eruption center might have varied during the period. The frequent volcanic activity should be at least one of the leading events to cause the momentous turnover of biota and the ecosystem during the great Permian-Triassic transition.
张素新袁鹏赵来时童金南杨浩于吉顺史玉芳
铵伊利石的高温相变被引量:6
2011年
对山西阳泉煤层黏土煤矸石中的铵伊利石进行了Fourier变换红外光谱分析、电子探针分析、元素分析、热重-差热分析和高温衍射分析。根据化学成分结果,按O_(10)(OH)_2及四面体阳离子数之和为4计算得其晶体化学式为:[(NH_4)_(0.65)K_(0.02)Na_(0.03)Ca_(0.01)]_(0.71)[Al_(2.04)Mg_(0.01)]_(2.05)[(Si_(3.14)Ti_(0.02)Al_(0.84))_4O_(10)](OH)_2。铵伊利石的晶体结构具有较好的热稳定性,晶体结构随温度的变化分为3个阶段:400℃以前结构保持稳定,层间[NH_4]^+表现为缓慢释放的特征;400~900℃层间[NH_4]^+分解,N快速释放,同时伴随着羟基脱除,表现为层间距缩小直至层状结构垮塌,但TOT结构单元层仍保持一定的完整性,[NH_4]^+分解的精确温度为573℃;900~1300℃为相变阶段,铵伊利石保留的不完整结构向非晶质转变,最后重新结晶生成莫来石和高温方石英。
吴红丹于吉顺张锦化雷新荣
关键词:晶体结构
浙江煤山牙形石微区原位REE组成及古环境意义被引量:3
2012年
本文利用激光剥蚀电感耦合等离子体质谱(LA-ICPMS),对煤山D剖面包含二叠纪-三叠纪界线层的牙形石中色变指数(CAI)较低的部分进行微区原位微量元素分析,并与利用溶解法测定的相应的沉积碳酸盐岩围岩稀土元素(REE)的组成进行了对比,探讨了它们的稀土元素组成对环境变化响应的差异及其可能的原因.结果显示,无论是稀土总量REE,还是Ce异常值,牙形石的微区原位REE信息比围岩更能反映出当时的环境变化.这表明牙形石化石比围岩对环境变化更加敏感,利用牙形石微区LA-ICPMS微量元素分析的方法是可靠的.同时,牙形石的Ce异常值还能对早三叠世的环境有较好的指示意义,为二叠纪与三叠纪之交大绝灭主幕开始到早三叠世环境的剧烈变化和长期缺氧环境提供了新的证据.
陈剑波赵来时陈中强童金南周炼胡兆初陈泳霖
关键词:牙形石LA-ICPMS煤山剖面地球化学
氯化钠增白煅烧高岭土的反应热力学被引量:8
2011年
采用氯化钠作为氯化剂氯化增白煅烧高岭土,并对相关反应进行化学热力学计算。结果表明,当氯化钠的添加量为6%,煅烧温度为900℃,煅烧时间为2h时,产品白度提高到92.3%,Fe2O3的去除率达到16.9%。其反应机理:在Al2O3参与的情况下,Fe2O3被氯化生成气态的FeCl3,900℃时,该反应的吉布斯自由能ΔrGΘm约为-350kJ/mol,且随着反应温度的提高,ΔrGΘm减小,有利于反应的进行。
张锦化吴红丹雷新荣于吉顺裴大婷李启超
关键词:煅烧高岭土增白热力学分析吉布斯自由能
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