The lining concrete of subsea tunnel services under combined hydraulic pressure, mechanical and environmental loads. The chloride ion and water penetrations into concrete under hydraulic pressure were investigated. The experimental results indicate that the water penetration depth, chloride ion transportation depth, and the concentration of chloride ion ingression into concrete increase with raised hydraulic pressure and hold press period. But the chloride ion transportation velocity is only 53% of that of water when concrete specimens are under hydraulic pressure. The chloride transportation coefficient of concrete decreases with hold press period as power function. And that would increase 500% 600% in chloride transportation coefficient when the hydraulic pressure increases from 0 to 1.2 MPa. The hydraulic pressure also decreases the bound chloride ion of concrete to about zero. Besides, the low water-cementitions materials and suitable content of mineral admixture(including fly ash and slag) improve the resistance capacity of chloride penetration, and binding capacity of concrete under hydraulic pressure.